[(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)

被引:0
作者
Tadbuppa, Primjira P. [2 ]
Tiekink, Edward R. T. [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
CARBONIMIDOTHIOATES; PH;
D O I
10.1107/S160053681000975X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The Au atom in the title compound, [Au(C(11)H(14)NOS)-(C(18)H(33)P)], is coordinated within an S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.060 (3) angstrom]. In the crystal structure, molecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H center dot center dot center dot pi.
引用
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页码:M421 / U800
页数:13
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