Effects of polymerization potential on the properties of electrosynthesized PEDOT films

被引：165
作者：
Du, X
Wang, Z [1 ]
机构：
[1] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
来源：
ELECTROCHIMICA ACTA | 2003年 / 48卷 / 12期
基金：
中国国家自然科学基金;
关键词：
electropolymerization; PEDOT; ESR;
D O I：
10.1016/S0013-4686(03)00143-9
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Poly(3,4-ethylenedioxythiophene) (PEDOT) films were prepared from an aqueous solution by electrooxidation at different anodic potential in the range 0.8-1.5 V (vs. SCE). The effect of polymerization potential on conductivity, electrochemical behavior and ESR response of PEDOT film has been investigated. The overoxidation peak of PEDOT exists near the polymerization potential of 3,4-ethylenedioxythiopbene. The overoxidation behavior of PEDOT with polymerization potential yielded bell-shaped curve of the conductivity of PEDOT and the polymerization rate with the polymerization potential. This phenomenon has been reported for the first time. (C) 2003 Elsevier Science Ltd. All rights reserved.
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收藏
页码：1713 / 1717
页数：5
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