Recent Advances in Electrocatalysts for Alkaline Hydrogen Oxidation Reaction

被引：88

作者：

Zhao, Ruopeng ^{[1
,2
]}

Yue, Xin ^{[1
]}

Li, Qinghua ^{[1
]}

Fu, Gengtao ^{[3
]}

Lee, Jong-Min ^{[2
]}

Huang, Shaoming ^{[1
]}

机构：

[1] Guangdong Univ Technol, Guangzhou Key Lab Low Dimens Mat & Energy Storage, Sch Mat & Energy, Guangzhou 510006, Peoples R China

[2] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore

[3] Nanjing Normal Univ, Jiangsu Key Lab New Power Batteries, Jiangsu Collaborat Innovat, Ctr Biomed Funct Mat,Sch Chem & Mat Sci, Nanjing 210023, Peoples R China

来源：

SMALL | 2021年 / 17卷 / 47期

基金：

中国国家自然科学基金;

关键词：

activity and stability control; electrocatalysts; hydrogen oxidation reaction; mechanisms; OXYGEN REDUCTION REACTION; MEMBRANE FUEL-CELLS; PT-BASED ELECTROCATALYSTS; HIGH-PERFORMANCE; DOPED CARBON; BIFUNCTIONAL CATALYSTS; ALLOY ELECTROCATALYSTS; EVOLUTION REACTION; METAL-CATALYSTS; BINARY ALLOY;

D O I：

10.1002/smll.202100391

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With the rapid development of anion-exchange membrane technology and adequate supply of high-performance non-noble metal oxygen reduction reaction (ORR) catalysts in alkaline media, the commercialization of anion exchange membrane fuel cells (AEMFCs) become possible. However, the kinetics of the anodic hydrogen oxidation reaction (HOR) in AEMFCs is significantly decreased compared to the HOR in proton exchange membrane fuel cells (PEMFCs). Therefore, it is urgent to develop HOR catalysts with low price, high activity, and robust stability. However, comprehensive timely reviews on this specific subject do not exist enough yet and it is necessary to update reported major achievements and to point out future investigation directions. In this review, the current reaction mechanisms on HOR are summarized and deeply understood. The debates between the mechanisms are greatly harmonized. Recent advances in developing highly active and stable electrocatalysts for the HOR are reviewed. Moreover, the side reaction control is for the first time systematically introduced. Finally, the challenges and future opportunities in the field of HOR catalysis are outlined.

引用

页数：28

共 170 条

[1] The hydrogen evolution reaction and hydrogen oxidation reaction on thin film PdAu alloy surfaces [J].

Al-Odail, Faisal A. ;

Anastasopoulos, Alexandros ;

Hayden, Brian E. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (37) :11398-11406

[2] Palladium/nickel bifunctional electrocatalyst for hydrogen oxidation reaction in alkaline membrane fuel cell [J].

Alesker, Maria ;

Page, Miles ;

Shviro, Meital ;

Paska, Yair ;

Gershinsky, Gregory ;

Dekel, Dario R. ;

Zitoun, David .

JOURNAL OF POWER SOURCES, 2016, 304 :332-339

[3] Platinum-Coated Copper Nanowires with High Activity for Hydrogen Oxidation Reaction in Base [J].

Alia, Shaun M. ;

Pivovar, Bryan S. ;

Yan, Yushan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (36) :13473-13478

[4] Unexpected hydrogen oxidation selectivity of Pt/NbTiO2 catalysts [J].

Banham, Dustin ;

Ye, Siyu ;

O'Toole, Alex ;

Lemke, Adam ;

Eisenbraun, Eric .

NANO ENERGY, 2016, 27 :157-166

[5] Heterogeneous recyclable nano-palladium catalyzed amidation of esters using formamides as amine sources [J].

Bao, Yong-Sheng ;

Wang, Lili ;

Jia, Meilin ;

Xu, Aiju ;

Agula, Bao ;

Baiyin, Menghe ;

Zhaorigetu, Bao .

GREEN CHEMISTRY, 2016, 18 (13) :3808-3814

[6] Palladium-Ceria Catalysts with Enhanced Alkaline Hydrogen Oxidation Activity for Anion Exchange Membrane Fuel Cells [J].

Bellini, Marco ;

Pagliaro, Maria V. ;

Lenarda, Anna ;

Fornasiero, Paolo ;

Marelli, Marcello ;

Evangelisti, Claudio ;

Innocenti, Massimo ;

Jia, Qingying ;

Mukerjee, Sanjeev ;

Jankovic, Jasna ;

Wang, Lianqin ;

Varcoe, John R. ;

Krishnamurthy, Chethana B. ;

Grinberg, Ilya ;

Davydova, Elena ;

Dekel, Dario R. ;

Miller, Hamish A. ;

Vizza, Francesco .

ACS APPLIED ENERGY MATERIALS, 2019, 2 (07) :4999-5008

[7] Palladium Nanoparticle-Graphitic Carbon Nitride Porous Synergistic Catalyst for Hydrogen Evolution/Oxidation Reactions over a Broad Range of pH and Correlation of Its Catalytic Activity with Measured Hydrogen Binding Energy [J].

Bhowmik, Tanmay ;

Kundu, Manas Kumar ;

Barman, Sudip .

ACS CATALYSIS, 2016, 6 (03) :1929-1941

[8] An Anion-Exchange Membrane Fuel Cell Containing Only Abundant and Affordable Materials [J].

Biemolt, Jasper ;

Douglin, John C. ;

Singh, Ramesh K. ;

Davydova, Elena S. ;

Yan, Ning ;

Rothenberg, Gadi ;

Dekel, Dario R. .

ENERGY TECHNOLOGY, 2021, 9 (04)

[9] Pt/C catalyst impregnated with tungsten-oxide - Hydrogen oxidation reaction vs. CO tolerance [J].

Brkovic, Snezana M. ;

Nikolic, Vladimir M. ;

Kaninski, Milica P. Marceta ;

Pasti, Igor A. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (26) :13364-13372

[10] Investigating Silver Nanoparticle Interactions with Quaternary Ammonium Functionalized Triblock Copolymers and Their Effect on Midblock Crystallinity [J].

Buggy, Nora C. ;

Du, Yifeng ;

Kuo, Mei-Chen ;

Gasvoda, Ryan J. ;

Seifert, Soenke ;

Agarwal, Sumit ;

Coughlin, E. Bryan ;

Herring, Andrew M. .

ACS APPLIED POLYMER MATERIALS, 2020, 2 (11) :4914-4923

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