Ultra High Electrical Performance of Nano Nickel Oxide and Polyaniline Composite Materials

被引:34
作者
Cai, Xiaomin [1 ,2 ]
Cui, Xiuguo [1 ]
Zu, Lei [1 ,2 ]
Zhang, You [1 ,2 ]
Gao, Xing [1 ,2 ]
Lian, Huiqin [3 ]
Liu, Yang [1 ]
Wang, Xiaodong [2 ]
机构
[1] Beijing Inst Petrochem Technol, Coll Mat Sci & Engn, Beijing 102617, Peoples R China
[2] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
[3] Beijing Inst Petrochem Technol, Beijing Key Lab Specialty Elastomer Composite Mat, Beijing 102617, Peoples R China
基金
中国国家自然科学基金; 北京市自然科学基金;
关键词
nano nickel oxide; polyaniline; redox electrolyte; supercapacitor; ELECTROCHEMICAL CAPACITORS; SUPERCAPACITOR APPLICATION; FLEXIBLE SUPERCAPACITORS; NANOCOMPOSITE ELECTRODE; ENERGY DENSITY; FABRICATION; GRAPHENE; NANOPARTICLES; CYCLODEXTRIN; NANOFIBERS;
D O I
10.3390/polym9070288
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The cooperative effects between the PANI (polyaniline)/nano-NiO (nano nickel oxide) composite electrode material and redox electrolytes (potassium iodide, KI) for supercapacitor applications was firstly discussed in this article, providing a novel method to prepare nano-NiO by using beta-cyelodextrin (beta-CD) as the template agent. The experimental results revealed that the composite electrode processed a high specific capacitance (2122.75 F.g(-1) at 0.1 A.g(-1) in 0.05 M KI electrolyte solution), superior energy density (64.05 Wh.kg(-1) at 0.2 A.g(-1) in the two-electrode system) and excellent cycle performance (86% capacitance retention after 1000 cycles at 1.5 A.g(-1)). All those ultra-high electrical performances owe to the KI active material in the electrolyte and the PANI coated nano-NiO structure.
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页数:14
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