Water-mediated proton conduction in Ni(ii) and Co(ii) benzenetriphosphonates

被引：12

作者：

Feng, Lu ^{[1
]}

Pan, Zhi-Quan ^{[1
]}

Zhou, Hong ^{[1
]}

Zhou, Min ^{[2
]}

Hou, Hao-Bo ^{[2
]}

机构：

[1] Wuhan Inst Technol, Coll Chem & Environm Technol, Wuhan 430073, Hubei, Peoples R China

[2] Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430072, Hubei, Peoples R China

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 44期

关键词：

METAL-ORGANIC FRAMEWORK; SULFONATE-CARBOXYLATE LIGANDS; COMPOSITE MEMBRANE; MOF; TEMPERATURE; POLYMER; LUMINESCENT; RANGE; STATE;

D O I：

10.1039/c9dt02960e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel transition metal compounds, [Ni(4,4 '-bipyH)(2)(H2O)(4)].2(H(4)bmt).9H(2)O (1) and [Co(4,4 '-bipy)(H2O)(4)][Co(4,4 '-bipyH)(2)(H2O)(4)].2(H(3)bmt).6H(2)O (2), have been synthesized. They possess continuous H-bond networks and high-density [PO3] groups, which give conductivity values in the order of 10(-3) S cm(-1) in a wide temperature range and 98% relative humidity.

引用

页码：16493 / 16496

页数：4

共 41 条

[1] Proton conductive metal phosphonate frameworks [J].

Bao, Song-Song ;

Shimizu, George K. H. ;

Zheng, Li-Min .

COORDINATION CHEMISTRY REVIEWS, 2019, 378 :577-594

[2] Co-Ca Phosphonate Showing Humidity-Sensitive Single Crystal to Single Crystal Structural Transformation and Tunable Proton Conduction Properties [J].

Bao, Song-Song ;

Li, Nan-Zhu ;

Taylor, Jared M. ;

Shen, Yang ;

Kitagawa, Hiroshi ;

Zheng, Li-Min .

CHEMISTRY OF MATERIALS, 2015, 27 (23) :8116-8125

[3] Enhancing Proton Conduction in 2D Co-La Coordination Frameworks by Solid-State Phase Transition [J].

Bao, Song-Song ;

Otsubo, Kazuya ;

Taylor, Jared M. ;

Jiang, Zheng ;

Zheng, Li-Min ;

Kitagawa, Hiroshi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (26) :9292-9295

[4] Tuning Proton Conductivity in Alkali Metal Phosphonocarboxylates by Cation Size-Induced and Water-Facilitated Proton Transfer Pathways [J].

Bazaga-Garcia, Montse ;

Papadaki, Maria ;

Colodrero, Rosario M. P. ;

Olivera-Pastor, Pascual ;

Losilla, Enrique R. ;

Nieto-Ortega, Belen ;

Aranda, Miguel Angel G. ;

Choquesillo-Lazarte, Duane ;

Cabeza, Aurelio ;

Demadis, Konstantinos D. .

CHEMISTRY OF MATERIALS, 2015, 27 (02) :424-435

[5] Guest Molecule-Responsive Functional Calcium Phosphonate Frameworks for Tuned Proton Conductivity [J].

Bazaga-Garcia, Montse ;

Colodrero, Rosario M. P. ;

Papadaki, Maria ;

Garczarek, Piotr ;

Zon, Jerzy ;

Olivera-Pastor, Pascual ;

Losilla, Enripe R. ;

Leon-Reina, Laura ;

Aranda, Miguel A. G. ;

Choquesillo-Lazarte, Duane ;

Demadis, Konstantinos D. ;

Cabeza, Aurelio .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (15) :5731-5739

[6] On the decay of Nafion proton conductivity at high temperature and relative humidity [J].

Casciola, M. ;

Alberti, G. ;

Sganappa, M. ;

Narducci, R. .

JOURNAL OF POWER SOURCES, 2006, 162 (01) :141-145

[7] Structural Variability in Multifunctional Metal Xylenediaminetetraphosphonate Hybrids [J].

Colodrero, Rosario M. P. ;

Angeli, Giasemi K. ;

Bazaga-Garcia, Montse ;

Olivera-Pastor, Pascual ;

Villemin, Didier ;

Losilla, Enrique R. ;

Martos, Estefania Q. ;

Hix, Gary B. ;

Aranda, Miguel A. G. ;

Demadis, Konstantinos D. ;

Cabeza, Aurelio .

INORGANIC CHEMISTRY, 2013, 52 (15) :8770-8783

[8] Multifunctional Luminescent and Proton-Conducting Lanthanide Carboxyphosphonate Open-Framework Hybrids Exhibiting Crystalline-to-Amorphous-to-Crystalline Transformations [J].

Colodrero, Rosario M. P. ;

Papathanasiou, Konstantinos E. ;

Stavgianoudaki, Nikoleta ;

Olivera-Pastor, Pascual ;

Losilla, Enrique R. ;

Aranda, Miguel A. G. ;

Leon-Reina, Laura ;

Sanz, Jesus ;

Sobrados, Isabel ;

Choquesillo-Lazarte, Duane ;

Garcia-Ruiz, Juan M. ;

Atienzar, Pedro ;

Rey, Fernando ;

Demadis, Konstantinos D. ;

Cabeza, Aurelio .

CHEMISTRY OF MATERIALS, 2012, 24 (19) :3780-3792

[9] Multifunctional lanthanum tetraphosphonates: Flexible, ultramicroporous and proton-conducting hybrid frameworks [J].

Colodrero, Rosario M. P. ;

Olivera-Pastor, Pascual ;

Losilla, Enrique R. ;

Aranda, Miguel A. G. ;

Leon-Reina, Laura ;

Papadaki, Maria ;

McKinlay, Alistair C. ;

Morris, Russell E. ;

Demadis, Konstantinos D. ;

Cabeza, Aurelio .

DALTON TRANSACTIONS, 2012, 41 (14) :4045-4051

[10] A tetranuclear Cu4(μ3-OH)2-based metal-organic framework (MOF) with sulfonate-carboxylate ligands for proton conduction [J].

Dong, Xi-Yan ;

Wang, Rui ;

Li, Jia-Bin ;

Zang, Shuang-Quan ;

Hou, Hong-Wei ;

Mak, Thomas C. W. .

CHEMICAL COMMUNICATIONS, 2013, 49 (90) :10590-10592

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