Water-mediated proton conduction in Ni(ii) and Co(ii) benzenetriphosphonates

被引：12
作者：
Feng, Lu [1 ]
Pan, Zhi-Quan [1 ]
Zhou, Hong [1 ]
Zhou, Min [2 ]
Hou, Hao-Bo [2 ]
机构：
[1] Wuhan Inst Technol, Coll Chem & Environm Technol, Wuhan 430073, Hubei, Peoples R China
[2] Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430072, Hubei, Peoples R China
来源：
DALTON TRANSACTIONS | 2019年 / 48卷 / 44期
关键词：
METAL-ORGANIC FRAMEWORK; SULFONATE-CARBOXYLATE LIGANDS; COMPOSITE MEMBRANE; MOF; TEMPERATURE; POLYMER; LUMINESCENT; RANGE; STATE;
D O I：
10.1039/c9dt02960e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel transition metal compounds, [Ni(4,4 '-bipyH)(2)(H2O)(4)].2(H(4)bmt).9H(2)O (1) and [Co(4,4 '-bipy)(H2O)(4)][Co(4,4 '-bipyH)(2)(H2O)(4)].2(H(3)bmt).6H(2)O (2), have been synthesized. They possess continuous H-bond networks and high-density [PO3] groups, which give conductivity values in the order of 10(-3) S cm(-1) in a wide temperature range and 98% relative humidity.
引用
收藏
页码：16493 / 16496
页数：4
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