A Single-Step Synthesis of Enynes: Pd-Catalyzed Arylalkynylation of Aryl Iodides, Internal Alkynes, and Alkynylsilanes

被引：53

作者：

Sakai, Norio ^{[1
]}

Komatsu, Ryosuke ^{[1
]}

Uchida, Naoki ^{[1
]}

Ikeda, Reiko ^{[1
]}

Konakahara, Takeo ^{[1
]}

机构：

[1] Tokyo Univ Sci RIKADAI, Dept Pure & Appl Chem, Fac Sci & Technol, Chiba 2788510, Japan

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 06期

关键词：

CROSS-COUPLING REACTIONS; ONE-POT SYNTHESIS; EFFICIENT SYNTHESIS; TERMINAL ALKYNES; TETRASUBSTITUTED OLEFINS; SONOGASHIRA REACTIONS; CONJUGATED DIENYNES; SELECTIVE SYNTHESIS; ARYLBORONIC ACIDS; ORGANIC HALIDES;

D O I：

10.1021/ol100180j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An unprecedented single-step synthesis of enyne derivatives through Pd-catalyzed arylalkynylation of aryl iodides, Internal alkynes, and alkynylsilanes is described.

引用

页码：1300 / 1303

页数：4

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