Ionic liquid promotes N2 coordination to titanocene(III) monochloride

被引：10
作者：
Katayama, Akira [1 ]
Inomata, Tomohiko [2 ]
Ozawa, Tomohiro [1 ,2 ]
Masuda, Hideki [2 ]
机构：
[1] Nagoya Inst Technol, Grad Sch Engn, Dept Cooperat Major Nanopharmaceut Sci, Showa Ku, Nagoya, Aichi 4668555, Japan
[2] Nagoya Inst Technol, Grad Sch Engn, Dept Life Sci & Appl Chem, Showa Ku, Nagoya, Aichi 4668555, Japan
来源：
DALTON TRANSACTIONS | 2017年 / 46卷 / 24期
关键词：
ELECTROCATALYTIC CO2 REDUCTION; ROOM-TEMPERATURE; ELECTROCHEMICAL REDUCTION; ATMOSPHERIC-PRESSURE; AMMONIA-SYNTHESIS; NITROGEN BONDS; PROTON SOURCE; AU ELECTRODE; COMPLEXES; TITANIUM;
D O I：
10.1039/c7dt01063j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Coordination of N-2 to [(Cp2TiCl)(2)] in a non-coordinating ionic liquid, Pyr(4)FAP, was studied by UV-vis/NIR and EPR spectroscopies. [(Cp2TiCl)(2)] is in equilibrium between monomeric [Cp2TiCl] and dimeric species [(Cp2TiCl)(2)]. The frozen solution EPR spectrum revealed the coordination of N-2 to [Cp2TiCl], suggesting that Pyr(4)FAP promotes N-2 coordination to the Ti(III) center.
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收藏
页码：7668 / 7671
页数：4
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