Rumphellclovane A, a novel clovane-related sesquiterpenoid from the gorgonian coral Rumphella antipathies

被引：26

作者：

Chung, Hsu-Ming ^{[1
,2
]}

Chen, Yung-Husan ^{[2
]}

Hwang, Tsong-Long ^{[3
]}

Chuang, Li-Fan ^{[2
,4
,5
,6
]}

Wang, Wei-Hsien ^{[1
,2
]}

Sung, Ping-Jyun ^{[1
,2
,4
,5
]}

机构：

[1] Natl Sun Yat Sen Univ, APORC, Dept Marine Biotechnol & Resources, Kaohsiung 804, Taiwan

[2] NMMBA, Checheng 944, Pingtung, Taiwan

[3] Chang Gung Univ, Grad Inst Nat Prod, Tao Yuan 333, Taiwan

[4] NDHU, Dept Life Sci, Grad Inst Marine Biotechnol, Checheng 944, Pingtung, Taiwan

[5] NDHU, Grad Inst Biotechnol, Checheng 944, Pingtung, Taiwan

[6] Natl Taiwan Univ, Inst Fisheries Sci, Taipei 106, Taiwan

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 20期

关键词：

Rumphella antipathies; Rumphellclovane; Clovane; Sesquiterpenoid; CARYOPHYLLANE;

D O I：

10.1016/j.tetlet.2010.03.046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel clovane-related derivative, rumphellclovane A (1), which was found to possess a new carbon skeleton, and a new natural clovane, 2 beta-hydroxyclovan-9-one (2), were isolated from the gorgonian coral Rumphella antipathies. The structures of metabolites 1 and 2 were elucidated by spectroscopic analysis and by comparison of the spectral data with those of related clovane analogues. A plausible biosynthetic pathway of 1 was proposed. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：2734 / 2736

页数：3

共 12 条

[1] The microbiological hydroxylation of some 2,9-dioxygenated clovanes by Mucor plumbeus [J].