An innovative approach to recover the metal values from spent lithium-ion batteries

被引：92
作者：
Barik, S. P. [1 ]
Prabaharan, G. [1 ]
Kumar, B. [1 ]
机构：
[1] Attero Recycling Pvt Ltd, Dept R&D, Roorkee 247661, Uttarakhand, India
来源：
WASTE MANAGEMENT | 2016年 / 51卷
关键词：
Lithium-ion batteries; Recycling; Washing; Precipitation; Roasting; VALUABLE METALS; COBALT; SEPARATION;
D O I：
10.1016/j.wasman.2015.11.004
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
A new approach to recover metal values from spent lithium-ion batteries with a simple and environmentally friendly method is investigated. Two stages of water washing of the mixed black powder resulted in satisfactory separation of cobalt and lithium. Lithium in the wash liquor is precipitated using saturated sodium carbonate solution. Cobalt oxide in the residue is purified by removing organic matrix through roasting followed by dilute acid washing. The purities of the products obtained during the processes are analyzed by Microwave Plasma-Atomic Emission Spectrophotometer and confirmed from X-ray diffraction analysis. The overall process is safe, economic and can be scaled up for commercial production. Based on the process steps involved, a flow sheet is proposed for industrial application. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：222 / 226
页数：5
相关论文
共 22 条
  • [1] Brauer G., 1963, Handbook of Preparative Inorganic Chemistry, V2nd Ed, P1520
  • [2] A laboratory-scale lithium-ion battery recycling process
    Contestabile, M
    Panero, S
    Scrosati, B
    [J]. JOURNAL OF POWER SOURCES, 2001, 92 (1-2) : 65 - 69
  • [3] An overview on the current processes for the recycling of batteries
    Espinosa, DCR
    Bernardes, AM
    Tenório, JAS
    [J]. JOURNAL OF POWER SOURCES, 2004, 135 (1-2) : 311 - 319
  • [4] Hydrometallurgical separation of aluminium, cobalt, copper and lithium from spent Li-ion batteries
    Ferreira, Daniel Alvarenga
    Zimmer Prados, Luisa Martins
    Majuste, Daniel
    Mansur, Marcelo Borges
    [J]. JOURNAL OF POWER SOURCES, 2009, 187 (01) : 238 - 246
  • [5] Gaines L.R. Cuenca., 2000, COSTS LITHIUM ION BA
  • [6] Development of a recycling process for Li-ion batteries
    Georgi-Maschler, T.
    Friedrich, B.
    Weyhe, R.
    Heegn, H.
    Rutz, M.
    [J]. JOURNAL OF POWER SOURCES, 2012, 207 : 173 - 182
  • [7] Greenwood N.N., 2012, Chemistry of the Elements
  • [8] Recovery of lithium and cobalt from waste lithium ion batteries of mobile phone
    Jha, Manis Kumar
    Kumari, Anjan
    Jha, Amrita Kumari
    Kumar, Vinay
    Hait, Jhumki
    Pandey, Banshi Dhar
    [J]. WASTE MANAGEMENT, 2013, 33 (09) : 1890 - 1897
  • [9] Recovery of cobalt sulfate from spent lithium ion batteries by reductive leaching and solvent extraction with Cyanex 272
    Kang, Jingu
    Senanayake, Gamini
    Sohn, Jeongsoo
    Shin, Shun Myung
    [J]. HYDROMETALLURGY, 2010, 100 (3-4) : 168 - 171
  • [10] Reductive leaching of cathodic active materials from lithium ion battery wastes
    Lee, CK
    Rhee, KI
    [J]. HYDROMETALLURGY, 2003, 68 (1-3) : 5 - 10
123