Research on the stability of heavy metals (Cu, Zn) in excess sludge with the pretreatment of thermal hydrolysis

被引:19
作者
Wu, Huimin [1 ]
Li, Meng [1 ]
Zhang, Lei [1 ]
Sheng, Chao [1 ]
机构
[1] Wuhan Univ Technol, Sch Civil Engn & Architecture, Wuhan 430070, Peoples R China
关键词
heavy metals; optimal conditions; stability; thermal hydrolysis; SEQUENTIAL EXTRACTION; SEWAGE-SLUDGE; METALLOTHIONEIN; BEHAVIOR;
D O I
10.2166/wst.2015.537
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Thermal hydrolysis (TH) has been used to improve anaerobic digestion performance as well as the stability of heavy metals in sludge. Because the toxicity of heavy metals is closely related to both the concentration and the chemical speciation, more exhaustive studies on speciation distribution are urgently needed. This research aimed to investigate the effects of TH treatment (especially the time and temperature) on the concentration and stability of heavy metals in sludge, and to define the optimal TH conditions. The TH experiment indicated that the content of the stable form of Cu and Zn reached 83% and 47.4%, respectively, with TH at 210 degrees C and 30 min. Compared with the raw sludge, the proportion of Cu and Zn increased by 11.88% and 7.3%, respectively. Results indicated that the heavy metals were combined with sludge in a more stable form with the pretreatment of TH, which improved the stability of heavy metals.
引用
收藏
页码:890 / 898
页数:9
相关论文
共 20 条
[1]   Study of metallothionein modified electrode surface behavior in the presence of heavy metal ions-biosensor [J].
Adam, V ;
Petrlova, J ;
Potesil, D ;
Zehnalek, J ;
Sures, B ;
Trnkova, L ;
Jelen, F ;
Kizek, R .
ELECTROANALYSIS, 2005, 17 (18) :1649-1657
[2]   Biosorption of cadmium by various types of dried sludge: An equilibrium study and investigation of mechanisms [J].
Choi, Sun Beom ;
Yun, Yeoung-Sang .
JOURNAL OF HAZARDOUS MATERIALS, 2006, 138 (02) :378-383
[3]   Effects of thermal and mechanical pretreatments of secondary sludge on biogas production under thermophilic conditions [J].
Climent, Mavi ;
Ferrer, Ivet ;
del Mar Baeza, Ma ;
Artola, Adriana ;
Vazquez, Felicitas ;
Font, Xavier .
CHEMICAL ENGINEERING JOURNAL, 2007, 133 (1-3) :335-342
[4]  
Conner J.R., 1990, Chemical Fixation and Solidification of Hazardous Wastes
[5]   Heavy metal bioaccumulation and metallothionein content in tissues of the sea bream Sparus aurata from three different fish farming systems [J].
Creti, Patrizia ;
Trinchella, Francesca ;
Scudiero, Rosaria .
ENVIRONMENTAL MONITORING AND ASSESSMENT, 2010, 165 (1-4) :321-329
[6]   Reducing the heavy metal content of sewage sludge by advanced sludge treatment methods [J].
Dewil, Raf ;
Baeyens, Jan ;
Neyens, Elisabeth .
ENVIRONMENTAL ENGINEERING SCIENCE, 2006, 23 (06) :994-999
[7]   Decreasing activated sludge thermal hydrolysis temperature reduces product colour, without decreasing degradability [J].
Dwyer, Jason ;
Starrenbury, Daniel ;
Tait, Stephan ;
Barr, Keith ;
Batstone, Damien J. ;
Lant, Paul .
WATER RESEARCH, 2008, 42 (18) :4699-4709
[8]   Characteristics of selected fractions of heavy metals in biologically and thermally transformed sewage sludge [J].
Koncewicz-Baran, Malgorzata ;
Orlowska, Kalina ;
Gondek, Krzysztof .
DESALINATION AND WATER TREATMENT, 2014, 52 (19-21) :3783-3789
[9]   Heavy metals uptake by sonicated activated sludge: Relation with floc surface properties [J].
Laurent, Julien ;
Casellas, Magali ;
Dagot, Christophe .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 162 (2-3) :652-660
[10]   Influence of thermal treatment on sequential extraction and leaching behaviour of trace metals in a contaminated sewage sludge [J].
Obrador, A ;
Rico, MI ;
Alvarez, JM ;
Novillo, J .
BIORESOURCE TECHNOLOGY, 2001, 76 (03) :259-264