Super absorbent, light, and highly flame retardant cellulose-based aerogel crosslinked with citric acid

被引:1
作者
Kaya, Mehmet [1 ]
机构
[1] Recep Tayyip Erdogan Univ, Dept Chem, Fac Arts & Sci, TR-53100 Rize, Turkey
关键词
aerogel; cellulose; citric acid; crosslinking; flame retardant; super absorbent; WASTE MATERIALS; SHAPE RECOVERY; LINKING; CARBON; HYDROGELS; ESTERIFICATION; ADSORPTION; BIOMASS; ENERGY; NANOCRYSTALS;
D O I
10.1002/APP.45315
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Light (0.089-0.12 g cm(-3)), superabsorbent (84-99 g water/1 g aerogel), and highly flame retardant non-crosslinked cellulose aerogel (CA) and crosslinked cellulose aerogel (CL-CA) have been successfully produced from pruning waste of blueberry tree. The prepared aerogels with three dimensional porous structure have a remarkably thermal stability and flame retardant performance, which totally burned after 136-200 s. Besides, CA and CL-CA have an important Brunauer-Emmet-Teller surface area, which are 348 and 275 m(2) g(-1), respectively. The concepts of this study are simple and bio-wastes are easily available and sustainable at low cost, and therefore, the current process is appropriate for industrial scale production and has a significant potential in the future of green materials. (C) 2017 Wiley Periodicals, Inc.
引用
收藏
页数:9
相关论文
共 62 条
[1]   Versatile Cellulose-Based Carbon Aerogel for the Removal of Both Cationic and Anionic Metal Contaminants from Water [J].
Alatalo, Sara-Maaria ;
Pileidis, Filoklis ;
Makila, Ermei ;
Sevilla, Marta ;
Repo, Eveliina ;
Salonen, Jarno ;
Sillanpaa, Mika ;
Titirici, Maria-Magdalena .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (46) :25875-25883
[2]  
Allan GG, 2013, CELL CHEM TECHNOL, V47, P1
[3]   Aerogel insulation for building applications: A state-of-the-art review [J].
Baetens, Ruben ;
Jelle, Bjorn Petter ;
Gustavsen, Arild .
ENERGY AND BUILDINGS, 2011, 43 (04) :761-769
[4]   Development of metal-matrix composites from industrial/agricultural waste materials and their derivatives [J].
Bahrami, A. ;
Soltani, N. ;
Pech-Canul, M. I. ;
Gutierrez, C. A. .
CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2016, 46 (02) :143-207
[5]   Superhydrophobic cellulose-based bionanocomposite films from Pickering emulsions [J].
Bayer, Ilker S. ;
Steele, Adam ;
Martorana, Philip J. ;
Loth, Eric ;
Miller, Lance .
APPLIED PHYSICS LETTERS, 2009, 94 (16)
[6]   Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions [J].
Beck-Candanedo, S ;
Roman, M ;
Gray, DG .
BIOMACROMOLECULES, 2005, 6 (02) :1048-1054
[7]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[8]   Cellulose aerogels from aqueous alkali hydroxide-urea solution [J].
Cai, Jie ;
Kimura, Satoshi ;
Wada, Masahisa ;
Kuga, Shigenori ;
Zhang, Lina .
CHEMSUSCHEM, 2008, 1 (1-2) :149-154
[9]  
Chan CH, 2013, BIORESOURCES, V8, P785
[10]   Ultralight and highly flexible aerogels with long cellulose I nanofibers [J].
Chen, Wenshuai ;
Yu, Haipeng ;
Li, Qing ;
Liu, Yixing ;
Li, Jian .
SOFT MATTER, 2011, 7 (21) :10360-10368