Highly Selective and Sensitive Trimethylamine Gas Sensor Based on Cobalt Imidazolate Framework Material

被引:161
作者
Chen, Er-Xia [1 ,2 ]
Fu, Hong-Ru [1 ]
Lin, Rui [1 ]
Tan, Yan-Xi [1 ]
Zhang, Jian [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
关键词
cobalt imidazolate framework; gas sensor; selectivity; trimethylamine; SENSING PROPERTIES; THERMAL-STABILITY; POLYMORPHISM; OXIDE;
D O I
10.1021/am5071317
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A cobalt imidazolate (im) framework material [Co(im)(2)](n) was employed to use as a trimethylamine (TMA) gas sensor and the [Co(im)(2)](n) sensor can be easily fabricated by using Ag-Pd interdigitated electrodes. Gas sensing measurement indicated that the [Co(im)(2)](n) sensor shows excellent selectivity, high gas response and a low detection limit level of 2 ppm to TMA at 75 degrees C. The good selectivity and high response to TMA of the sensor based on [Co(im)(2)](n) may be attributed to the weak interaction between the TMA molecules and the [Co(im)(2)](n) framework. That may provide an ideal candidate for detecting freshness of fish and seafood.
引用
收藏
页码:22871 / 22875
页数:5
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