Quest for metal/NH bifunctional bioinspired catalysis in a dinuclear platform

被引：52

作者：

Kuwata, Shigeki ^{[1
]}

Ikariya, Takao ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Appl Chem, Grad Sch Sci & Engn, Meguro Ku, Tokyo 1528552, Japan

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 12期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; BRIDGED DIIRIDIUM COMPLEXES; RU AMIDO COMPLEXES; N CHELATE LIGANDS; H BOND-CLEAVAGE; IMIDO COMPLEXES; OXIDATIVE ADDITION; C-H; CHIRAL RU; ORGANOIMIDO COMPLEXES;

D O I：

10.1039/b927357c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bifunctional catalysts, in which two functionalities cooperate in substrate activation and transformation, promote a number of chemical and biological reactions quite efficiently. This perspective mainly describes our efforts to extend the concept of the metal/NH bifunctional mononuclear catalysts to dinuclear systems. The late transition metal dinuclear complexes with bridging sulfonylated nitrogen donors and parent amides (NH(2)) are focused on particularly, while the chemistry of related nitrogen-bridged polynuclear complexes is also mentioned.

引用

页码：2984 / 2992

页数：9

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