Stereoselective synthesis and some reactions of β-(η6-arene)Cr(CO)3 complexes of podocarpic acid derivatives

被引：2

作者：

Clark, GR ^{[1
]}

Kuipers, B ^{[1
]}

Metzler, MR ^{[1
]}

Nguyen, MH ^{[1
]}

Woodgate, PD ^{[1
]}

机构：

[1] Univ Auckland, Dept Chem, Auckland 92019, New Zealand

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 545卷

关键词：

chromium; carbonyl; podocarpic acid derivatives; stereoselective synthesis; crystal structure;

D O I：

10.1016/S0022-328X(97)00220-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stereoselective synthesis of a number of (eta(6)-arene)tricarbonylchromium(0) complexes derived from podocarpic acid has been achieved in good to excellent yield. The stereochemistry of complexes 36 and 37 was established by X-ray crystallography. Reactions of some of the deprotonated complexes with electrophiles were investigated. (C) 1997 Elsevier Science S.A.

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收藏

页码：225 / 247

页数：23

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