Correlation of nitrogen related traps in InGaAsN with solar cell properties

被引:40
作者
Khan, Aurangzeb [1 ]
Kurtz, Sarah R.
Prasad, S.
Johnston, S. W.
Gou, Jihua
机构
[1] Univ S Alabama, Dept Elect & Comp Engn, Mobile, AL 36688 USA
[2] Natl Renewable Energy Lab, Golden, CO 80401 USA
[3] Univ S Alabama, Dept Mech Engn, Mobile, AL 36688 USA
关键词
D O I
10.1063/1.2747664
中图分类号
O59 [应用物理学];
学科分类号
摘要
The thermal annealing of nitrogen related traps in p-type InGaAsN and GaAsN is investigated by deep level transient spectroscopy (DLTS). Upon annealing, an apparent recovery of the photovoltaic properties correlates with changes in the DLTS data observed for InGaAsN and GaAsN diodes and solar cells, revealing that a nitrogen related E1 (E-C-0.20 eV) center has an important role in governing the solar cell performance. The large electron capture cross section (similar to 8.9x10(-15) cm(2)) of this center indicates that this defect may act as an efficient recombination center. Therefore, its complete removal by annealing or by some other process is essential for the high performance of GaInAsN solar cells. The internal quantum efficiency data were modeled to quantify the change in material properties associated with this improvement upon annealing. Annealed cells with indium impurity (InGaAsN) show a slightly higher photoresponse, which could be due to low scattering caused by In-N pair formation after annealing. (c) 2007 American Institute of Physics.
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页数:3
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共 9 条
[1]   Observed trapping of minority-carrier electrons in p-type GaAsN during deep-level transient spectroscopy measurement [J].
Johnston, SW ;
Kurtz, SR ;
Friedman, DJ ;
Ptak, AJ ;
Ahrenkiel, RK ;
Crandall, RS .
APPLIED PHYSICS LETTERS, 2005, 86 (07) :1-3
[2]   Deep levels in p- and n-type InGaAsN for high-efficiency multi-junction III-V solar cells [J].
Kaplar, RJ ;
Kwon, D ;
Ringel, SA ;
Allerman, AA ;
Kurtz, SR ;
Jones, ED ;
Sieg, RM .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 69 (01) :85-91
[3]   Electron traps in Ga(As,N) layers grown by molecular-beam epitaxy [J].
Krispin, P ;
Spruytte, SG ;
Harris, JS ;
Ploog, KH .
APPLIED PHYSICS LETTERS, 2002, 80 (12) :2120-2122
[4]   Capacitance-spectroscopy identification of a key defect in N-degraded GalnNAs solar cells [J].
Kurtz, S ;
Johnston, S ;
Branz, HM .
APPLIED PHYSICS LETTERS, 2005, 86 (11) :1-3
[5]   Effect of nitrogen concentration on the performance of Ga1-xInxNyAs1-y solar cells [J].
Kurtz, S ;
Johnston, SW ;
Geisz, JF ;
Friedman, DJ ;
Ptak, AJ .
CONFERENCE RECORD OF THE THIRTY-FIRST IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE - 2005, 2005, :595-598
[6]   Structural changes during annealing of GaInAsN [J].
Kurtz, S ;
Webb, J ;
Gedvilas, L ;
Friedman, D ;
Geisz, J ;
Olson, J ;
King, R ;
Joslin, D ;
Karam, N .
APPLIED PHYSICS LETTERS, 2001, 78 (06) :748-750
[7]   InGaAsN solar cells with 1.0 eV band gap, lattice matched to GaAs [J].
Kurtz, SR ;
Allerman, AA ;
Jones, ED ;
Gee, JM ;
Banas, JJ ;
Hammons, BE .
APPLIED PHYSICS LETTERS, 1999, 74 (05) :729-731
[8]   Projected performance of three- and four-junction devices using GaAs and GaInP [J].
Kurtz, SR ;
Myers, D ;
Olson, JM .
CONFERENCE RECORD OF THE TWENTY SIXTH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE - 1997, 1997, :875-878
[9]   Minority carrier diffusion, defects, and localization in InGaAsN, with 2% nitrogen [J].
Kurtz, SR ;
Allerman, AA ;
Seager, CH ;
Sieg, RM ;
Jones, ED .
APPLIED PHYSICS LETTERS, 2000, 77 (03) :400-402