Characterization of Rice Husk by Pyrolysis-Gas Chromatography-Mass Spectrometry

被引:2
作者
Xie, Xin-Ping [1 ]
Zhang, Xiao-Dong [1 ]
Chen, Lei [1 ]
Sun, Lai-Zhi [1 ]
Si, Hong-Yu [1 ]
机构
[1] Shandong Acad Sci, Energy Res Inst, Key Lab Biomass Gasificat Technol Shandong Prov, Jinan, Peoples R China
关键词
rice husk; biomass; pyrolysis-gas chromatography-mass spectrometry; fast pyrolysis;
D O I
10.1080/10739149.2014.961643
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The analysis of products from rice husk under different decomposition temperatures was investigated by pyrolysis-gas chromatography-mass spectrometry. Compounds of molecular weight among 50-400amu in the reaction products were identified. The products were characterized as unsaturated aliphatic hydrocarbons, carboxyolic acids, aromatics, phenols, and aldehydes/ketones. The results showed that pyrolysis temperature above 700 degrees C accelerated the generation of unsaturated aliphatic hydrocarbons. The minimum concentrations of carboxylic acids and aldehydes/ketones appeared at 800 and 900 degrees C, respectively, while the maximum levels of carboxylic acids, phenols, and aldehydes/ketones were obtained at 700 degrees C. The lowest concentration of aromatics was also obtained at 700 degrees C. These results are expected to serve as reference values for research and industrial production of biological oils.
引用
收藏
页码:65 / 73
页数:9
相关论文
共 50 条
  • [41] Characterization of syringyl and guaiacyl lignins in thermomechanical pulp from oil palm empty fruit bunch by pyrolysis-gas chromatography-mass spectrometry using ion intensity calibration
    Nakagawa-Izumi, Akiko
    H'ng, Yin Ying
    Mulyantara, Lilik Tri
    Maryana, Roni
    Vu Thang Do
    Ohi, Hiroshi
    INDUSTRIAL CROPS AND PRODUCTS, 2017, 95 : 615 - 620
  • [42] Fast Pyrolysis of Lignocellulosic Biomass Components Over CaO and Fe/CaO Catalysts by Pyrolysis-Gas Chromatography/Mass Spectrometry
    Sun, Laizhi
    Zhang, Xiaodong
    Chen, Lei
    Zhao, Baofeng
    Yang, Shuangxia
    Xie, Xinping
    JOURNAL OF BIOBASED MATERIALS AND BIOENERGY, 2017, 11 (05) : 527 - 531
  • [43] The discrimination of auto-motive clear coat paints indistinguishable by Fourier transform infrared spectroscopy via pyrolysis-gas chromatography-mass spectrometry
    Burns, DT
    Doolan, KP
    ANALYTICA CHIMICA ACTA, 2005, 539 (1-2) : 157 - 164
  • [44] Identification of Protein Binding Media Used in Chinese Cultural Relics by Pyrolysis-Gas Chromatography/Mass Spectrometry
    Wang, Na
    Gu, An
    Min, Jun-Rong
    Li, Guang-Hua
    Lei, Yong
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2020, 48 (01) : 90 - 96
  • [45] A pyrolysis-gas chromatography/mass spectrometry study of volatile compounds produced by wood-based materials
    Marchoubeh, Mahsa Lotfi
    Knight, Holli
    Horn, Gavin P.
    FIRE AND MATERIALS, 2024, 48 (05) : 542 - 550
  • [46] THERMAL-DEGRADATION OF SOME BENZYLTRIALKYLAMMONIUM SALTS USING PYROLYSIS-GAS CHROMATOGRAPHY MASS-SPECTROMETRY
    HASKINS, NJ
    MITCHELL, R
    ANALYST, 1991, 116 (09) : 901 - 903
  • [47] Analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) of sawdust with Al/SBA-15 catalysts
    Lu Qiang
    Li Wen-zhi
    Zhang Dong
    Zhu Xi-feng
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2009, 84 (02) : 131 - 138
  • [48] EVALUATION OF THE OXIDATION OF RICE HUSKS WITH SODIUM HYPOCHLORITE USING GAS CHROMATOGRAPHY-MASS SPECTROMETRY AND DIRECT ANALYSIS IN REAL TIME-MASS SPECTROMETRY
    Wang, Shou-Ze
    Fan, Xing
    Zheng, Ai-Li
    Lu, Yao
    Wei, Xian-Yong
    Zhao, Yun-Peng
    Wang, Rui-Yu
    Dou, You-Quan
    Wang, Ying-Hua
    Wang, Chu-Fan
    Zhang, Fan
    Shen, Yong
    Li, Chun-Yan
    Liu, Zheng
    Liu, De-Ying
    ANALYTICAL LETTERS, 2014, 47 (01) : 77 - 90
  • [50] Valorisation of tyre waste from a vulcanisation plant by catalytic pyrolysis - Experimental investigations using pyrolysis-gas chromatography-mass spectrometry and drop-tube-fixed-bed reactor
    Jerzak, Wojciech
    Wadrzyk, Mariusz
    Sieradzka, Malgorzata
    Magdziarz, Aneta
    ENERGY CONVERSION AND MANAGEMENT, 2024, 313