Triphenylamine-containing imine-linked porous organic network for luminescent detection and adsorption of Cr(vi) in water

被引:4
作者
Wang, Man [1 ,2 ]
Li, Han-Shu [1 ,2 ]
Ding, Xin [1 ,2 ]
Jiang, Lizan [1 ,2 ]
Wu, Pengyan [1 ,2 ]
Zheng, Ruiting [1 ,2 ]
Bao, Guoyue [1 ,2 ]
Liu, Guoliang [3 ]
Wang, Jian [1 ,2 ]
机构
[1] Jiangsu Normal Univ, Sch Chem & Mat Sci, Xuzhou 221116, Jiangsu, Peoples R China
[2] Jiangsu Normal Univ, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China
[3] Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China
关键词
ATOMIC-ABSORPTION-SPECTROMETRY; CR-VI ANIONS; FRAMEWORKS; SENSOR; NANOSHEETS; POLYMERS; CHROMIUM; PRECONCENTRATION; NANOPARTICLES; FLUORESCENCE;
D O I
10.1039/d2dt01046a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this study, an imine-linked luminescent porous organic network (PON) has been successfully synthesized by the Schiff-base condensation reaction between 1,2-diphenylethylenediamine and tris(4-formylphenyl)amine. It exhibits strong fluorescence in an aqueous dispersion and can be applied as a luminescent probe for Cr(vi) (CrO42- and Cr2O72-) with high selectivity and sensitivity (LOD for Cr2O72- and CrO42- were below 0.35 mu M and 0.4 mu M, respectively) in a turn-off manner. The possible luminescence sensing mechanism and the adsorption capacity of Cr(vi) are also discussed in detail.
引用
收藏
页码:10351 / 10356
页数:6
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