Synthesis, structure, and magnetic properties of a cyclic dimer of bis(hexafluoroacetylacetonato)-{1,3-bis(N-tert-butyl-N-oxylamino)-5-tert-butyl-benzene}manganese(II)

被引：21

作者：

Gorlitz, G ^{[1
]}

Hayamizu, T ^{[1
]}

Itoh, T ^{[1
]}

Matsuda, K ^{[1
]}

Iwamura, H ^{[1
]}

机构：

[1] Kyushu Univ, Inst Fundamental Res Organ Chem, Higashi Ku, Fukuoka 81281, Japan

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 08期

关键词：

D O I：

10.1021/ic971398b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cyclic dimer 1 was obtained by the reaction of the diradical 1,3-bis(N-tert-butyl-N-oxylamino)-5-tert-butylbenzene with Mn(hfac)(2). A spin transition occurs in 1 on cooling due to ferromagnetic coupling via the bidentate diradical ligand. The temperature dependence of the magnetic properties can be interpreted quantitatively in the frame of the HDvV formalism.

引用

页码：2083 / +

页数：4

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