CO2 conversion: the potential of porous-organic polymers (POPs) for catalytic CO2-epoxide insertion

被引：114

作者：

Alkordi, Mohamed H. ^{[1
,4
]}

Weselinski, Lukasz J. ^{[1
,5
]}

D'Elia, Valerio ^{[2
,6
]}

Barman, Samir ^{[2
]}

Cadiau, Amandine ^{[1
]}

Hedhili, Mohamed N. ^{[3
]}

Cairns, Amy J. ^{[1
]}

AbdulHalim, Rasha G. ^{[1
]}

Basset, Jean-Marie ^{[2
]}

Eddaoudi, Mohamed ^{[1
]}

机构：

[1] King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Adv Membranes & Porous Mat Ctr, Funct Mat Design Discovery & Dev Res Grp FMD3, Thuwal 239556900, Saudi Arabia

[2] King Abdullah Univ Sci & Technol, KCC, Thuwal 239556900, Saudi Arabia

[3] King Abdullah Univ Sci & Technol, Imaging & Characterizat Lab, Thuwal 239556900, Saudi Arabia

[4] Zewail City Sci & Technol, Ctr Mat Sci, Giza 12588, Egypt

[5] Michigan Technol Univ, Dept Chem, 1400 Townsend Dr, Houghton, MI 49931 USA

[6] Vidyasirimedhi Inst Sci & Technol, Dept Mat Sci & Engn, Wangchan 21210, Rayong, Thailand

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 19期

关键词：

CONJUGATED MICROPOROUS POLYMERS; CYCLIC CARBONATE SYNTHESIS; CHEMICAL FIXATION; SALEN COMPLEXES; DIOXIDE UTILIZATION; ETHYLENE CARBONATE; LINEAR CARBONATES; CYCLOADDITION; FRAMEWORK; EPOXIDES;

D O I：

10.1039/c5ta09321j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Novel porous organic polymers (POPs) have been synthesized using functionalized Cr and Co-salen complexes as molecular building blocks. The integration of metalosalen catalysts into the porous polymer backbone permits the successful utilization of the resultant functionalized material as a solid-state catalyst for CO2-epoxide cycloaddition reactions with excellent catalytic performance under mild conditions of temperature and pressure. The catalysts proved to be fully recyclable and robust, thus showing the potential of POPs as smart functional materials for the heterogenization of key catalytic elements.

引用

页码：7453 / 7460

页数：8

共 98 条

[1] Polymer-bound aluminium salen complex as reusable catalysts for CO2 insertion into epoxides [J].