Boron chelates in the synthesis of α,β-unsaturated ketones of the coumarin series

被引：17

作者：

Manaev, A. V. ^{[1
]}

Chibisova, T. A. ^{[1
]}

Traven, V. F. ^{[1
]}

机构：

[1] DI Mendeleev Russian Univ Chem Technol, Moscow 125047, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2006年 / 55卷 / 12期

关键词：

coumarins; alpha; beta-enones; boron complexes; aldol condensation; electronic absorption spectra; fluorescence;

D O I：

10.1007/s11172-006-0576-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Condensation of aromatic aldehydes with 3(8)-acetyl-4(7)-difluoroboryloxycoumarin intramolecular complexes gave boron complexes of alpha,beta-unsaturated ketones, whose hydrolysis afforded the corresponding hydroxy cinnamoylcoumarins. The boron complexes and their hydrolysis products intensely absorb and fluoresce in the visible region of the spectrum.

引用

页码：2226 / 2232

页数：7

共 8 条

[1] THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].

DEWAR, MJS ;

ZOEBISCH, EG ;

HEALY, EF ;

STEWART, JJP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909

[2] On silicium compounds. [J].

Dilthey, W .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1903, 36 :3207-3213

[3] Synthesis and structures of boron complexes of acyl hydroxy coumarins [J].

Manaev, A. V. ;

Chibisova, T. A. ;

Lyssenko, K. A. ;

Antipin, M. Yu. ;

Traven, V. F. .

RUSSIAN CHEMICAL BULLETIN, 2006, 55 (11) :2091-2094

[4] EXPERIMENTS WITH SUBSTITUTED (3,2-C)-PYRANYL-2, 10-DIONES AND BENZOPYRANYL-(3,2-C) PYRAN-2,8-DIONES [J].

MUSTAFA, A ;

NAWAR, AA ;

HSIHMAT, OH ;

ZAYED, SMA .

TETRAHEDRON, 1963, 19 (11) :1831-&

[5] REACTIONS OF 4-HYDROXY-6-METHYL-2-PYRONE AND 6-SUBSTITUTED 4-HYDROXYCOUMARINS WITH ALPHABETA-UNSATURATED ACYL CHLORIDES [J].

SHIZURI, Y ;

KATO, K ;

HIRATA, Y ;

MUROBUSH.A ;

YAMAMURA, S .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1969, (19) :2774-&

[6] Polymethine dyes derived from boron complexes of, acetylhydroxycoumarins [J].

Traven, VF ;

Chibisova, TA ;

Manaev, AV .

DYES AND PIGMENTS, 2003, 58 (01) :41-46

[7]

TRAVEN VF, 2000, ZH OBSHCH KHIM, V0070

[8]

TRAVEN VF, 2000, ZH OBSHCH KHIM, V70, P847

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