Synthesis, Structure, and Cyclic Voltammetric Property of Metal String Complex [Ni3(dpa)4(ClO4)(Cl)]•CH2Cl2

被引：8

作者：

Miao, Xiao-He ^{[1
]}

Zhu, Long-Guan ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 05期

基金：

中国国家自然科学基金;

关键词：

X-ray diffraction; Metal string complex; Cyclic voltammetry; Axial mono-replacement; Nickel; CRYSTAL-STRUCTURE; BONDING INTERACTION; MOLECULAR WIRES; LIGANDS; CHAINS; OXIDATION; POLYMER;

D O I：

10.1002/zaac.200900396

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The metal string complex [Ni-3(dpa)(4)(ClO4)(Cl)] CH2Cl2 (1) [dpa = bis(2 pyridyl)amine] with different axial ligands was synthesized and characterized by elemental analysis, IR, UV/Vis, and fluorescence spectroscopy and TG analysis The molecular structure was determined by single crystal X ray analysis and its electrochemical properties were investigated This metal string complex is the first example with different axial ligands and in its structure a different structural packing relative to the metal string complex [Ni-3(dpa)(4)(Cl)(2)] (2) with two axial chloride ligands is generated The intense C-H pi interactions observed for 1 provide additional stability The axial mono substitution of Cl- by ClO4- in 1 relative to 2 results in one obviously short Ni-Ni distance and a higher stability towards oxidation

引用

页码：878 / 881

页数：4

共 50 条

[41] Synthesis and Crystal Structure of the [Re2(CH3COO)2Cl4((CH3)2NCOCH3)2] Complex
S. G. Mel'nik
Ya. E. Filinchuk
A. V. Shtemenko
Russian Journal of Coordination Chemistry, 2004, 30 : 786 - 791
[42] FORMATION AND CRYSTAL-STRUCTURE OF THE COMPLEX [(18-CROWN-6)(CH2CL2)2]
JONES, PG
HIEMISCH, O
BLASCHETTE, A
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (06): : 852 - 854
[43] Synthesis and crystal structure of [Cu(dpq)2(ClO4)](ClO4)•1.5CHCl3 (dpq=2,3-di-2-pyridylquinoxaline)
Liu, H
Zhong, BH
JOURNAL OF CHEMICAL RESEARCH-S, 2004, (02): : 123 - 124
[44] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE AMIDO PALLADATE (PPH4)2[PD2CL4(NH2)2].CH2CL2 AND OF THE BENZAMIDINE PALLADATE PPH4([PH-C(NH2)(NH)]PDCL3).CH3CN
VONARNIM, H
MASSA, W
ZINN, A
DEHNICKE, K
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (08): : 992 - 998
[45] Synthesis, structure and property of a metal sulfochloride-Hg3S2Cl2
Chen, Hua-Long
Kuang, Han-Mao
Chen, Wen-Tong
Ying, Shao-Ming
Liu, Jiu-Hui
JOURNAL OF CHEMICAL RESEARCH, 2009, (07) : 430 - 432
[46] Synthesis and crystal structure of the oxovanadium(V) complex [VOL(C9H6NO)] • CH2Cl2
Deng Zhao-Peng
Gao Shan
Zhao Hui
Huo Li-Hua
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (01) : 173 - 176
[47] Synthesis and Magnetic Properties of a Dimerized Trinuclear Ni String Complex, [Ni6Cl2(dpa)8](I5)2•0.25I2 (dpa-=2,2′-Dipyridylamide Anion)
Aoki, Kentaro
Otsubo, Kazuya
Yoshida, Yukihiro
Kimura, Yojiro
Sugimoto, Kunihisa
Kitagawa, Hiroshi
INORGANIC CHEMISTRY, 2021, 60 (21) : 16029 - 16034
[48] Further investigations of linear trirhodium complexes: experimental and theoretical studies of [Rh3(dpa)4Cl2] and [Rh3(dpa)4Cl2](BF4) [dpa = bis(2-pyridyl)amido anion]
Huang, Gin-Chen
Liu, Isiah Po-Chun
Kuo, Jau-Huei
Huang, Yi-Lin
Yeh, Chen-Yu
Lee, Gene-Hsiang
Peng, Shie-Ming
DALTON TRANSACTIONS, 2009, (14) : 2623 - 2629
[49] Synthesis, crystal structure, and properties of a novel coordination polymer constructed from a trinickel string core of [Ni3(Dpa)4]2+ and pyrazine-2,3-dicarboxylate
Zhang, J.
Zhu, L. G.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (09) : 660 - 663
[50] Synthesis and molecular structure of the tetranuclear μ4-oxo-centered chromium complex [Cr4(CH2CH2CH2NMe2)4(μ4-O)(μ-Cl)6]
Ossola, F
Benetollo, F
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 580 (01) : 56 - 59

← 1 2 3 4 5 →