Synthesis, Structure, and Cyclic Voltammetric Property of Metal String Complex [Ni3(dpa)4(ClO4)(Cl)]•CH2Cl2

被引：8

作者：

Miao, Xiao-He ^{[1
]}

Zhu, Long-Guan ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 05期

基金：

中国国家自然科学基金;

关键词：

X-ray diffraction; Metal string complex; Cyclic voltammetry; Axial mono-replacement; Nickel; CRYSTAL-STRUCTURE; BONDING INTERACTION; MOLECULAR WIRES; LIGANDS; CHAINS; OXIDATION; POLYMER;

D O I：

10.1002/zaac.200900396

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The metal string complex [Ni-3(dpa)(4)(ClO4)(Cl)] CH2Cl2 (1) [dpa = bis(2 pyridyl)amine] with different axial ligands was synthesized and characterized by elemental analysis, IR, UV/Vis, and fluorescence spectroscopy and TG analysis The molecular structure was determined by single crystal X ray analysis and its electrochemical properties were investigated This metal string complex is the first example with different axial ligands and in its structure a different structural packing relative to the metal string complex [Ni-3(dpa)(4)(Cl)(2)] (2) with two axial chloride ligands is generated The intense C-H pi interactions observed for 1 provide additional stability The axial mono substitution of Cl- by ClO4- in 1 relative to 2 results in one obviously short Ni-Ni distance and a higher stability towards oxidation

引用

页码：878 / 881

页数：4

共 50 条

[31] Synthesis and structure of a new dimanganese complex [Mn2(μ-OAc)2(phen)4](ClO4)2
Chen, H
Zhang, XF
Huang, DG
Chen, CN
Liu, QT
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (01) : 103 - 107
[32] Effects of Electric Field on the Structures of Metal String Complexes M3(dpa)4Cl2 (M=Co, Rh, Ir; dpa=dipyridylamide)
Huang Yan
Huang Xiao
Xu Xuan
ACTA PHYSICO-CHIMICA SINICA, 2013, 29 (06) : 1225 - 1232
[33] Synthesis and Structure of a New Dimanganese Complex [Mn2（μ-OAc）2（phen）4]（ClO4）2
陈惠
张晓峰
黄德光
陈昌能
刘秋田
Chinese Journal of Structural Chemistry, 2006, (01) : 103 - 107
[34] The oxochlorotantalates (PPh4)2[Ta2OCl9]2 • 2 CH2Cl2, (PPh4)2[Ta2OCl10] • 2 CH3CN, and (K-18-crown-6)4[Ta4O6Cl12] • 12 CH2Cl2
Noll, A
Müller, U
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (10): : 1721 - 1725
[35] Synthesis and crystal structure of mononuclear nickel(II) complex [Ni(IDB)2][C6H4(OH)COO]•ClO4•CH3CH2OH•H2O
Chen, YG
Liao, ZR
Hu, ZQ
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 21 (03) : 317 - 320
[36] A trinuclear nickel(II) complex with alternating square-planar and octahedral geometries.: Synthesis, crystal structure and magnetic properties of [Ni3(oxen)2(en)][ClO4]2
Chen, ZN
Zhang, HX
Yu, KB
Su, CY
Kang, BS
POLYHEDRON, 1998, 17 (09) : 1535 - 1540
[37] Unexpected complexation of allylpseudothiohydantoin hydrochlorides towards CuX (X=Cl, NO3, ClO4, BF4, 1/2SiF6). The first known examples of joint CuI(Cl,ClO4) and CuI(Cl,BF4) -complexes
Fedorchuk, A. A.
Kinzhybalo, V. V.
Slyvka, Yu. I.
Goreshnik, E. A.
Bednarchuk, T. J.
Lis, T.
Mys'kiv, M. G.
JOURNAL OF COORDINATION CHEMISTRY, 2017, 70 (05) : 871 - 884
[38] Synthesis, crystal structure and optical property of a novel metal chalcohalide: ZnHg3Se2Cl4
Zhang, Guodong
Xiong, Wei-Wei
Nie, Lina
Zhang, Qichun
JOURNAL OF SOLID STATE CHEMISTRY, 2015, 230 : 182 - 185
[39] Syntheses, molecular structures and properties of (Ph4P)2[trans-O2RuCl4]•CH2Cl2 and [(Ph3P)2N]2[trans-O2RuCl4]•CH2Cl2
Zhang, Zhi-Cui
Jiao, Yan-Ping
Lu, Dan-Dan
Jia, Ai-Quan
Zhang, Qian-Feng
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2025, 80 (3-4): : 129 - 134
[40] Synthesis and crystal structure of the [Re2(CH3COO)2Cl4((CH3)2NCOCH3)2] complex
Mel'nik, SG
Filinchuk, YE
Shtemenko, AV
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2004, 30 (11) : 786 - 791

← 1 2 3 4 5 →