Comparison of the Catalytic Activity of Gold Nanoparticles Supported in Ceria and Incarcerated in Styrene Copolymer

被引:24
作者
Perez, Yolanda [1 ,2 ]
Aprile, Carmela
Corma, Avelino [1 ]
Garcia, Hermenegildo [1 ]
机构
[1] Univ Politecn Valencia, Inst Univ Tecnol Quim, CSIC, Valencia 46022, Spain
[2] Univ Rey Juan Carlos, Madrid 28933, Spain
关键词
Gold catalysts; Aerobic oxidation; Alkyne coupling; AEROBIC OXIDATION; ALCOHOLS; IMINES; AMINES;
D O I
10.1007/s10562-009-0243-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The catalytic activity of gold nanoparticles supported on nanoparticulated ceria or incarcerated in a styrene copolymer has been compared for three general gold catalyzed reactions, namely the aerobic benzylamine and aniline oxidations and for phenylacetylene-amine-benzaldehyde coupling. Remarkable differences between the activity of both catalysts were observed.
引用
收藏
页码:204 / 209
页数:6
相关论文
共 14 条
  • [1] Catalysis by gold
    Bond, GC
    Thompson, DT
    [J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1999, 41 (3-4): : 319 - 388
  • [2] Nanocrystalline CeO2 increases the activity of an for CO oxidation by two orders of magnitude
    Carrettin, S
    Concepción, P
    Corma, A
    Nieto, JML
    Puntes, VF
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (19) : 2538 - 2540
  • [3] Supported gold nanoparticles as catalysts for organic reactions
    Corma, Avelino
    Garcia, Hermenegildo
    [J]. CHEMICAL SOCIETY REVIEWS, 2008, 37 (09) : 2096 - 2126
  • [4] Highly active and selective gold catalysts for the aerobic oxidative condensation of benzylamines to imines and one-pot, two-step synthesis of secondary benzylamines
    Grirrane, Abdessamad
    Corma, Avelino
    Garcia, Hermenegildo
    [J]. JOURNAL OF CATALYSIS, 2009, 264 (02) : 138 - 144
  • [5] Gold-Catalyzed Synthesis of Aromatic Azo Compounds from Anilines and Nitroaromatics
    Grirrane, Abdessamad
    Corma, Avelino
    Garcia, Hermenegildo
    [J]. SCIENCE, 2008, 322 (5908) : 1661 - 1664
  • [6] Size- and support-dependency in the catalysis of gold
    Haruta, M
    [J]. CATALYSIS TODAY, 1997, 36 (01) : 153 - 166
  • [7] Gold-catalyzed organic reactions
    Hashmi, A. Stephen K.
    [J]. CHEMICAL REVIEWS, 2007, 107 (07) : 3180 - 3211
  • [8] Gold catalysis
    Hashmi, A. Stephen K.
    Hutchings, Graham J.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (47) : 7896 - 7936
  • [9] Aerobic oxidation of alcohols under mild conditions catalyzed by novel polymer-incarcerated, carbon-stabilized gold nanoclusters
    Lucchesi, Celine
    Inasaki, Takeshi
    Miyamura, Hiroyuki
    Matsubara, Ryosuke
    Kobayashi, Shu
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (13) : 1996 - 2000
  • [10] Polymer incarcerated gold catalyzed aerobic oxidation of hydroquinones and their derivatives
    Miyamura, Hiroyuki
    Shiramizu, Mika
    Matsubara, Ryosuke
    Kobayashi, Shu
    [J]. CHEMISTRY LETTERS, 2008, 37 (03) : 360 - 361