Synthesis and catalytic activity of the Fe(II) and Fe(III) complexes with a new polydentate ligand containing an amide donor

被引：16

作者：

Gutkina, EA ^{[1
]}

Rubtsova, TB ^{[1
]}

Shteinman, AA ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia

来源：

KINETICS AND CATALYSIS | 2003年 / 44卷 / 01期

关键词：

D O I：

10.1023/A:1022580903767

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The iron complexes [Fe2+ (tpcaH)(MeCN)(2)](ClO4)(2) (I) and [Fe2O(tpca)(2)(H2O)(2)](ClO4)(2) (II) based on the new potentially tetradentate ligand bis(2-pyridyl)methyl-2-pyridylearboxamide (tpcaH) with the amide donor group inside the molecule were synthesized. The composition of the complexes was confirmed by elemental and mass spectrometric analyses and various spectral methods. Compounds I and II exhibited good catalytic activity in the stereospecific oxidation of alkanes by hydrogen peroxide.

引用

页码：106 / 111

页数：6

共 16 条

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