CuCr1-xNixO2 thin films prepared by chemical solution deposition

被引:7
作者
Lin, Yi-Han [1 ]
Yu, Bing-Shen [1 ]
Lei, Chien-Ming [2 ,3 ]
Fu, Yongsheng [4 ]
Park, Joon-Hyeong [5 ]
Chiu, Te-Wei [1 ]
机构
[1] Natl Taipei Univ Technol, Dept Mat & Mineral Resources Engn, 1 Zhongxiao E Rd Sec 3, Taipei 106, Taiwan
[2] Chinese Culture Univ, Dept Chem & Mat Engn, Taipei 11114, Taiwan
[3] Chinese Culture Univ, Grad Inst Nanomat, Taipei 11114, Taiwan
[4] Nanjing Univ Sci & Technol, Minist Educ, Key Lab Soft Chem & Funct Mat, Nanjing 210094, Jiangsu, Peoples R China
[5] Purdue Univ, Birck Nanotechnol Ctr, W Lafayette, IN 47907 USA
关键词
Delafossite compound; p-type semiconductors; CuCrO2; Chemical solution deposition; Transparent conducting oxides; ELECTRICAL-PROPERTIES; CUCRO2; PERFORMANCE; PROPERTY;
D O I
10.1016/j.tsf.2018.04.011
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
CuCr1-xNixO2, (0.0 <= x <= 0.4) thin films were prepared on non-alkali glass substrates by chemical solution deposition. The effects of Ni content in CuCr1-xNixO2 thin films on the microstructural, optical, electrical, and magnetic properties were investigated. X-ray diffraction analysis revealed that all the samples presented the delafossite structure. The transmittance of the CuCr1-xNixO2 thin films was above 60% in the visible region, and the band gap was between 3.02 and 3.17 eV. It was found that the electrical resistance was decreased by increasing doping amount of Ni2+ ions. The lowest resistivity with relatively high carrier concentration was obtained in CuCr0.6Ni0.4O2 thin films. The experimental results imply that it is possible to get higher electrical conductivity of p-type transparent conducting oxides from CuCrO2 via doping with divalent ions.
引用
收藏
页码:705 / 710
页数:6
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