[Cu(mim)4]2[α-Mo8O26] - A layer-type octamolybdate framework

被引：5

作者：

Alam, Nure ^{[1
]}

Feldmann, Claus ^{[1
]}

机构：

[1] KIT, Inst Inorgan Chem, D-76131 Karlsruhe, Germany

来源：

SOLID STATE SCIENCES | 2010年 / 12卷 / 04期

关键词：

Layer-type copper molybdate; Synthesis; Crystal structure; Characterization; COORDINATION POLYMERS; POLYOXOMETALATE CHEMISTRY; CLUSTERS; LIGAND; OXIDE; TRANSFORMATION; COMPLEXES; NETWORKS; SUBUNITS; ISOMERS;

D O I：

10.1016/j.solidstatesciences.2009.12.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By reaction of (NH4)(6)Mo7O24 center dot 4H(2)O, Cu(NO3)(2)center dot 2.5H(2)O and 1-methylimidazole (mim) under hydrothermal conditions the novel copper molybdate [Cu(mim)(4)](2)[alpha-Mo8O26] is obtained in the form of blue, rectangular-shaped crystals. The title compound crystallizes with monoclinic lattice symmetry in the space group P2(1)/n. The predominant structural feature of the title compound is a two-dimensional framework that is constituted by [alpha-Mo8O26](4-) octamolybdate units as framework nods and the copper complex [Cu(mim)(4)](2+) as a linker. In addition to single-crystal structure analysis [Cu(mim)(4)](2)[alpha-Mo8O26] is characterized by powder diffraction as well as by FT-IR and UV-vis spectroscopy. (C) 2009 Elsevier Masson SAS. All rights reserved.

引用

页码：471 / 475

页数：5

共 50 条

[41] Hydrothermal Syntheses and Crystal Structures of Compounds Based on α- or β-[Mo8O26]4− Isomers
Lancui Zhang
Yi Zhao
Wansheng You
Zaiming Zhu
Cuiying Huang
Journal of Cluster Science, 2010, 21 : 93 - 103
[42] A new polyoxomolybdate infinite chain complex containing β-[Mo8O26]4- linked up by two bonded Ag+ ions:: {(Bu4N)2Ag2[Mo8O26]}n
Chen, SM
Lu, CZ
Yu, YQ
Zhang, QZ
He, X
INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (09) : 1041 - 1044
[43] The ionothermal synthesis of a new 3-D framework based on classic β-[Mo8O26]4- anions
Lu, Kun
Zhu, Zihan
Peng, Lin
Fu, Hai
Wang, Xinlong
Wang, Enbo
JOURNAL OF COORDINATION CHEMISTRY, 2020, 73 (02) : 255 - 265
[44] Plastic electrode decorated with polyhedral anion tetrabutylammonium octamolybdate [N(C4H9)4]4 Mo8O26 for nM phosphate electrochemical detection
Figueredo, Federico
Girolametti, Federico
Aneggi, Eleonora
Lekka, Maria
Annibaldi, Anna
Susmel, Sabina
ANALYTICA CHIMICA ACTA, 2021, 1161
[45] TRINUCLEAR OXOTHIOMOLYBDATES FROM THE REDUCTIVE CLEAVAGE OF [MO8O26]4- WITH HEXAMETHYLDISILTHIANE
DO, YK
SIMHON, ED
HOLM, RH
INORGANIC CHEMISTRY, 1985, 24 (18) : 2827 - 2832
[46] Complexation and Isomerization of [β-Mo8O26]4-in the Presence of Ag+and DMF
Chupina, A., V
Mukhacheva, A. A.
Abramov, P. A.
Sokolov, M. N.
JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 61 (02) : 299 - 308
[47] Composite solids constructed from one-dimensional coordination polymer matrices and molybdenum oxide subunits: Polyoxomolybdate clusters within [{Cu(4,4'-bpy)}(4)Mo8O26] and [{Ni(H2O)(2)(4,4'-bpy)(2)}(2)Mo8O26] and one-dimensional oxide chains in [{Cu(4,4'-bpy)}(4)Mo15O47]center dot 8H(2)O
Hagrman, D
Zubieta, C
Rose, DJ
Zubieta, J
Haushalter, RC
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (08): : 873 - 876
[48] Synthesis, Characterization and Structure of [Fe(2,2'-bipy)3]2[α-Mo8O26]: An α-Octamolybdate-Supported Compound Formed During the Diffuse Process
Li, Qiang
Wu, Pingfan
Yin, Panchao
Zhang, Jin
Shi, Lu
Wei, Yongge
JOURNAL OF CLUSTER SCIENCE, 2010, 21 (02) : 181 - 186
[49] Supramolecular isomerism with polythreaded topology based on [Mo8O26]4- isomers
Lan, Ya-Qian
Li, Shun-Li
Wang, Xin-Long
Shao, Kui-Zhan
Su, Zhong-Min
Wang, En-Bo
INORGANIC CHEMISTRY, 2008, 47 (02) : 529 - 534
[50] Synthesis, Characterization and Structure of [Fe(2,2′-bipy)3]2[α-Mo8O26]: An α-Octamolybdate-Supported Compound Formed During the Diffuse Process
Qiang Li
Pingfan Wu
Panchao Yin
Jin Zhang
Lu Shi
Yongge Wei
Journal of Cluster Science, 2010, 21 : 181 - 186

← 1 2 3 4 5 →