[Cu(mim)4]2[α-Mo8O26] - A layer-type octamolybdate framework

被引：5

作者：

Alam, Nure ^{[1
]}

Feldmann, Claus ^{[1
]}

机构：

[1] KIT, Inst Inorgan Chem, D-76131 Karlsruhe, Germany

来源：

SOLID STATE SCIENCES | 2010年 / 12卷 / 04期

关键词：

Layer-type copper molybdate; Synthesis; Crystal structure; Characterization; COORDINATION POLYMERS; POLYOXOMETALATE CHEMISTRY; CLUSTERS; LIGAND; OXIDE; TRANSFORMATION; COMPLEXES; NETWORKS; SUBUNITS; ISOMERS;

D O I：

10.1016/j.solidstatesciences.2009.12.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By reaction of (NH4)(6)Mo7O24 center dot 4H(2)O, Cu(NO3)(2)center dot 2.5H(2)O and 1-methylimidazole (mim) under hydrothermal conditions the novel copper molybdate [Cu(mim)(4)](2)[alpha-Mo8O26] is obtained in the form of blue, rectangular-shaped crystals. The title compound crystallizes with monoclinic lattice symmetry in the space group P2(1)/n. The predominant structural feature of the title compound is a two-dimensional framework that is constituted by [alpha-Mo8O26](4-) octamolybdate units as framework nods and the copper complex [Cu(mim)(4)](2+) as a linker. In addition to single-crystal structure analysis [Cu(mim)(4)](2)[alpha-Mo8O26] is characterized by powder diffraction as well as by FT-IR and UV-vis spectroscopy. (C) 2009 Elsevier Masson SAS. All rights reserved.

引用

页码：471 / 475

页数：5

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