Nanoscaled rutile active phase in Mo-V-Nb-O supported catalysts for the oxidation of propane to acrylic acid

被引：31
作者：
Lopez-Medina, Ricardo [2 ]
Fierro, J. L. G. [2 ]
Olga Guerrero-Perez, M. [1 ]
Banares, Miguel A. [2 ]
机构：
[1] Univ Malaga, Dept Ingn Quim, Escuela Ingn, E-29071 Malaga, Spain
[2] CSIC, Inst Catalisis & Petroleoquim, E-28049 Madrid, Spain
来源：
APPLIED CATALYSIS A-GENERAL | 2010年 / 375卷 / 01期
关键词：
Propane; Acrylic acid; V-Mo-O; V-Mo-Al-O; Rutile; Oxidation; Structure-activity relationship; In situ Raman; XRD; XPS; SN/V/NB/SB MIXED OXIDES; SELECTIVE OXIDATION; STRUCTURAL-CHARACTERIZATION; VSBO4; CATALYSTS; ACETIC-ACID; AMMOXIDATION; SB; ETHANE; DEHYDROGENATION; PERFORMANCE;
D O I：
10.1016/j.apcata.2009.12.017
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Alumina-stabilized nanosized rutile Mo-V-Nb-O oxide phases are prepared, characterized and used for the selective oxidation of propane to acrylic acid. Coverage on alumina support, atomic Mo/V molar ratio and calcination conditions (inert vs. oxidizing) affect the structure and catalytic performance. The effect of Mo/V ratio is opposite depending on calcination atmosphere. Segregated molybdenum oxides are not efficient while partially reduced rutile-type mixed molybdenum-vanadium oxide phases are efficient for the conversion of propane to acrylic acid. Niobium species would have a structural effect, stabilizing mixed molybdenum-vanadium oxide phases. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：55 / 62
页数：8
相关论文
共 55 条
[1]   Bulk structure and catalytic properties of mixed Mo-V-Sb-Nb oxides for selective propane oxidation to acrylic acid [J].
Al-Saeedi, JN ;
Guliants, VV ;
Guerrero-Pérez, O ;
Bañares, MA .
JOURNAL OF CATALYSIS, 2003, 215 (01) :108-115
[2]   Effect of the modified support γ-Al2O3-CaO on the structure and hydrodesulfurization activity of Mo and Ni-Mo catalysts [J].
Andonova, S. ;
Vadov, Ch. ;
Pawelec, B. ;
Shtereva, I. ;
Tyuliev, G. ;
Damyanova, S. ;
Petrov, L. .
APPLIED CATALYSIS A-GENERAL, 2007, 328 (02) :201-209
[3]   The control of catalytic performance of rutile-type Sn/V/Nb/Sb mixed oxides, catalysts for propane ammoxidation to acrylonitrile [J].
Arcozzi, Elena ;
Ballarini, Nicola ;
Cavani, Fabrizio ;
Cimini, Massimo ;
Lucarelli, Carlo ;
Trifiro, Ferruccio ;
Delichere, Pierre ;
Millet, Jean-Marc M. ;
Marion, Philippe .
CATALYSIS TODAY, 2008, 138 (1-2) :97-103
[4]   Nb 3d and O 1s core levels and chemical bonding in niobates [J].
Atuchin, VV ;
Kalabin, IE ;
Kesler, VG ;
Pervukhina, NV .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2005, 142 (02) :129-134
[5]   Propane oxidation on MoVTeNbO mixed oxide catalysts: study of the phase composition of active and selective catalysts [J].
Baca, M ;
Pigamo, A ;
Dubois, JL ;
Millet, JMM .
TOPICS IN CATALYSIS, 2003, 23 (1-4) :39-46
[6]   The role of Sb and Nb in rutile-type Sn/V/Nb/Sb mixed oxides, catalysts for propane ammoxidation to acrylonitrile [J].
Ballarini, Nicola ;
Cavani, Fabrizio ;
Di Memmo, Sergio ;
Zappoli, Francesca ;
Marion, Philippe .
CATALYSIS TODAY, 2009, 141 (3-4) :264-270
[7]   Structure-activity relationships in alumina-supported molybdena-vanadia catalysts for propane oxidative dehydrogenation [J].
Bañares, MA ;
Khatib, SJ .
CATALYSIS TODAY, 2004, 96 (04) :251-257
[8]   Molecular structures of supported metal oxide catalysts under different environments [J].
Bañares, MA ;
Wachs, IE .
JOURNAL OF RAMAN SPECTROSCOPY, 2002, 33 (05) :359-380
[9]   Structural Characterization of Operating Catalysts by Raman Spectroscopy [J].
Banares, Miguel A. ;
Mestl, Gerhard .
ADVANCES IN CATALYSIS, VOL 52, 2009, 52 :43-128
[10]   V2O5-MoO3 catalysts for benzene oxidation [J].
Bielanski, A ;
Najbar, M .
APPLIED CATALYSIS A-GENERAL, 1997, 157 (1-2) :223-261
123456