Synthesis and structural diversity of oligosilanylzinc compounds

被引：26

作者：

Gaderbauer, Walter ^{[1
]}

Balatoni, Istvan ^{[1
]}

Wagner, Harald ^{[1
]}

Baumgartner, Judith ^{[1
]}

Marschner, Christoph ^{[1
]}

机构：

[1] Graz Univ Technol, Inst Anorgan Chem, A-8010 Graz, Austria

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 06期

关键词：

CONJUGATE ADDITION; DIASTEREOSELECTIVE ADDITION; CATALYZED SILYLZINCATION; ZINC REAGENTS; SILYL-METALS; R-ASTERISK; ZN-ATE; HALIDES; ENHANCEMENT; DERIVATIVES;

D O I：

10.1039/b910463a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of potassium oligosilanyls with ZnCl2 lead to the formation of oligosilanylzinc compounds with zinc's coordination sphere expanded by ligation of TMEDA, an additional oligosilanyl group, or a chloride ion.

引用

页码：1598 / 1603

页数：6

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