Iron(II)-bis(isonitrile) complexes: novel catalysts in asymmetric transfer hydrogenations of aromatic and heteroaromatic ketones

被引：76

作者：

Naik, Anu ^{[1
]}

Maji, Tapan ^{[1
]}

Reiser, Oliver ^{[1
]}

机构：

[1] Univ Regensburg, Inst Organ Chem, D-93053 Regensburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 25期

关键词：

IRON COMPLEX; POLAR BONDS; LIGANDS;

D O I：

10.1039/c0cc00508h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral iron(II)-bis(isonitrile) complexes catalyse the transfer hydrogenation of aromatic ketones with enantioselectivities up to 91% ee, most likely via hydride transfer through imine intermediates, generated by in situ reduction of the isonitrile ligands, whereas iron acts as a Lewis acid to activate the ketone.

引用

页码：4475 / 4477

页数：3

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