Experimental study on the fire protection properties of PVC sheath for old and new cables

被引:62
作者
Xie, Qiyuan [1 ]
Zhang, Heping [1 ]
Tong, Lin [1 ]
机构
[1] USTC, State Key Lab Fire Sci, Hefei 230027, Peoples R China
基金
中国博士后科学基金;
关键词
Fire protection property; Old cable; Atmosphere; TG-FTIR; MCC; TG-FTIR ANALYSIS; THERMAL-DEGRADATION; PYROLYSIS;
D O I
10.1016/j.jhazmat.2010.03.015
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The objective of the present study is to analyze the fire protection properties of old and new cables through TG, FTIR and MCC experiments. The results show that the mass loss of old cable sheath is clearly larger than the new one when the temperature is higher than 550 K in air or nitrogen atmosphere. It suggests that the old cable sheath starts to pyrolyze generally at the same temperature based on the analysis of the onset temperatures of mass loss. The results also show that there is a main peak DTG for the old and new cable sheath under each condition. However, the main peak DTG of old cable sheath is larger than that of the new cable sheath, especially in air atmosphere. The FTIR experiments show that the HCI is released by the new cable later but more quickly than the old cable. The MCC experiments suggest that compared with the new one, the peak heat release rate is larger for the old cable. It illustrates that the old cable sheath generally pyrolyzes and combusts more strongly and completely than the new one. Namely, the fire protection properties of the old cable in old buildings are relatively weak. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:373 / 381
页数:9
相关论文
共 13 条
  • [1] Babrauskasa V., 1992, ENG PLAST APPL, V18, P255
  • [2] Thermal degradation of PVC cable insulation studied by simultaneous TG-FTIR and TG-EGA methods
    Benes, M
    Milanov, N
    Matuschek, G
    Kettrup, A
    Placek, V
    Balek, V
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2004, 78 (02) : 621 - 630
  • [3] Cheng J. Q, 2007, FIRE SCI TECH, V26, P383
  • [4] Toward the understanding of the thermal degradation of commercially available fire-resistant cable
    Henrist, C
    Rulmont, A
    Cloots, R
    Gilbert, B
    Bernard, A
    Beyer, G
    [J]. MATERIALS LETTERS, 2000, 46 (2-3) : 160 - 168
  • [5] The study of thermal pyrolysis mechanisms for chloro organic compounds in electric cable and medical wastes
    Ma, RH
    Lin, YC
    Kuo, CP
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2006, 75 (02) : 245 - 251
  • [6] *MPS FIRE BUR, 2006, 2005 STAT YB CHINA
  • [7] *MPS FIRE BUR, 2006, 2003 STAT YB CHINA
  • [8] *MPS FIRE BUR, 2005, 2004 STAT YB CHINA
  • [9] *MPS FIRE BUR, 2009, 2008 STAT YB CHINA
  • [10] *MPS FIRE BUR, 2007, 2006 STAT YB CHINA