Synthesis and Characterization of Zn3(P1-xAsxO4)2 • 4H2O and α-Zn3(P1-xAsxO4)2 (0 ≤ x ≤ 0.29) substitutional solid solutions

被引：0

作者：

Viter, VN ^{[1
]}

Nagornyi, PG ^{[1
]}

Zubko, AV ^{[1
]}

机构：

[1] Shevchenko Natl Univ, UA-252017 Kiev, Ukraine

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 49卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zn-3(P1-xAsxO4)(2) (.) 4H(2)O and alpha-Zn-3(P1-xAsxO4)(2) (0 less than or equal to x less than or equal to 0.29) substitutional solid solutions are synthesized and characterized by chemical analysis, X-ray powder diffraction, and IR spectroscopy. The former crystallizes in an orthorhombic system (space group Pnma); the latter, in a monoclinic system (space group A2/a). The unit cell dimensions and volumes of both vary linearly with x. The thermolysis of Zn-3(P1-xAsxO4)(2) (.) 4H(2)O is studied by thermal analysis.

引用

页码：1467 / 1471

页数：5