Linking of metal centres through boryl ligands:: synthesis, spectroscopic and structural characterisation of a symmetrically bridged boryl complex CpFe(CO)2BO2C6H2O2BFe(CO)2Cp

被引：13

作者：

Aldridge, S

Calder, RJ

Dickinson, AA

Willock, DJ

Steed, JW

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

[2] Kings Coll London, Dept Chem, London WC2R 2LS, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 15期

关键词：

D O I：

10.1039/b003901m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis, spectroscopic and structural characterisation of the symmetrically bridged boryl complex CpFe(CO)(2)- BO2C6H2O2BFe(CO)(2)Cp are reported, together with analysis of the bonding by structural and DFT methods.

引用

页码：1377 / 1378

页数：2

共 21 条

[1]

ALDRIDGE S, 2000, IN PRESS J ORGANOMET

[2]

BAERENDS EJ, 1999, THEORETICAL CHEM

[3] DENSITY-FUNCTIONAL EXCHANGE-ENERGY APPROXIMATION WITH CORRECT ASYMPTOTIC-BEHAVIOR [J].

BECKE, AD .

PHYSICAL REVIEW A, 1988, 38 (06) :3098-3100

[4]

Braunschweig H, 1998, ANGEW CHEM INT EDIT, V37, P1786, DOI 10.1002/(SICI)1521-3773(19980803)37:13/14<1786::AID-ANIE1786>3.0.CO

[5]

2-C

[6]

Braunschweig H, 1998, EUR J INORG CHEM, P291

[7] Diboran(4)yl groups as ligands to transition metals [J].

Braunschweig, H ;

Ganter, B ;

Koster, M ;

Wagner, T .

CHEMISCHE BERICHTE, 1996, 129 (09) :1099-1101

[8]

Braunschweig H, 1998, EUR J INORG CHEM, P465

[9] TRANSITION-METAL-PROMOTED HYDROBORATIONS OF ALKENES, EMERGING METHODOLOGY FOR ORGANIC TRANSFORMATIONS [J].

BURGESS, K ;

OHLMEYER, MJ .

CHEMICAL REVIEWS, 1991, 91 (06) :1179-1191

[10] Phosphine exchange reactions involving cis-[Pt(PPh3)2(Bcat)2] (cat=1,2-O2C6H4) and the oxidative addition of 1,2-B2Cl2(NMe2)2 to Pt0 [J].

Curtis, D ;

Lesley, MJG ;

Norman, NC ;

Orpen, AG ;

Starbuck, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (10) :1687-1694

← 1 2 3 →