A new zinc-zinc-bonded compound with a dianionic α-diimine ligand:: synthesis and structure of [Na(THF)2]2•[LZn-ZnL] (L = [(2,6-iPr2C6H3)N(Me)C]22-)

被引:91
作者
Yang, Xiao-Juan [1 ]
Yu, Jie
Liu, Yanyan
Xie, Yaoming
Schaefer, Henry F.
Liang, Yongmin
Wu, Biao
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[3] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[4] Univ Georgia, Ctr Computat Chem, Athens, GA 30602 USA
[5] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
关键词
D O I
10.1039/b703200e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and structure of a Zn-Zn-bonded compound supported by a doubly reduced alpha-diimine ligand, [Na(THF)(2)](2)center dot [LZn-ZnL] (L = [(2,6-(Pr2C6H3)-Pr-i)N(Me)C](2)(2-)) are reported, with a Zn-Zn bond length of 2.399(1) angstrom.
引用
收藏
页码:2363 / 2365
页数:3
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