Facile synthesis of stoichiometric AgSbS2 silk-like nanoflowers for solar energy conversion

被引:7
作者
Han, Minmin [1 ,2 ]
Jia, Junhong [1 ]
Wang, Wenzhen [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
Semiconductors; Nanocrystalline materials; Thin films; AgSbS2 Silk-like nanoflowers; Solvothermal chemical process; Photovoltaic absorption material; CELLS; FILMS; NANOCRYSTALS; GROWTH;
D O I
10.1016/j.matlet.2016.05.075
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In order to avoid the impurity phase, such as Ag3SbS3 and Sb2S3 among AgSbS2 particles and simplify the complicated steps in synthesizing AgSbS2 via conventional methods, the cubic AgSbS2 silk-like nano flowers with well-defined crystalline structure were synthesized by the one-step, facile and practical solvothermal chemical process. The results show that the as-prepared stoichiometric AgSbS2 nano flowers with the diameter of 1 mu m are comprised of silk-like ultrathin nanoflakes. Moreover, the possible formation mechanism of AgSbS2 silk-like nanoflowers with PSS (poly (sodium-p-styrenesul-fonate)) is studied. Furthermore, the AgSbS2 nanoflowers exhibit a broad absorption and high value of incident photon to current conversion efficiency (IPCE) in visible light range, indicating that it is a promising photovoltaic absorption material. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:130 / 133
页数:4
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