Photovoltaic solar electrochemical oxidation (PSEO) for treatment of lignosulfonate wastewater

被引:44
作者
Dominguez-Ramos, Antonio [1 ]
Aldaco, Ruben [1 ]
Irabien, Angel [1 ]
机构
[1] Univ Cantabria, Dept Quim Inorgan & Ingn Quim, E-39005 Santander, Spain
关键词
electrochemical oxidation; kinetics; mathematical modelling; photovoltaic solar energy; diamond boron-doped electrodes; lignosulfonate; THIN-FILM ELECTRODES; DIRECT CONNECTION BEHAVIOR; DOPED DIAMOND ELECTRODES; ORGANIC POLLUTANTS; DISINFECTION; BATTERIES; EFFLUENT; ENERGY; ELECTRODIALYSIS; DESALINATION;
D O I
10.1002/jctb.2370
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
BACKGROUND: Under the current global energy scenario, the need for self-sustainable processes is encouraged. The photovoltaic solar powered electrochemical oxidation (PSEO) process has been developed to remove the organic matter from a lignosulfonate wastewater. RESULTS: An electrochemical reactor using boron-doped diamond electrodes, in a batch configuration, is directly supplied with current from a set of photovoltaic solar modules. Experimental results show that the process can oxidize about 90% of the total organic carbon (TOC) of the organic matter in the wastewater under the described operating conditions. CONCLUSION: The technical suitability of the PSEO process has been demonstrated. A model to relate solar irradiance and electrical current was applied and used in a kinetic expression which depends on solar irradiance to describe the removal of TOC. (C) 2010 Society of Chemical Industry
引用
收藏
页码:821 / 830
页数:10
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