Li-Deficient Materials-Decoration Restrains Oxygen Evolution Achieving Excellent Cycling Stability of Li-Rich Mn-Based Cathode

被引：12
作者：
Ji, Xueqian [1 ,2 ]
Xu, Yuxing [1 ,3 ]
Xia, Qing [1 ,3 ]
Zhou, Yuncheng [1 ,2 ]
Song, Jiechen [1 ,2 ]
Feng, Hailan [1 ,3 ]
Wang, Pengfei [1 ,3 ]
Yang, Jun [1 ]
Tan, Qiangqiang [1 ,2 ]
机构：
[1] Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
[3] Hebei Technol Innovat Ctr Adv Energy Mat, Langfang 065001, Peoples R China
来源：
ACS APPLIED MATERIALS & INTERFACES | 2022年 / 14卷 / 26期
基金：
中国国家自然科学基金;
关键词：
KEYWORDS; lithium-ion batteries; layered cathode; oxygen evolution; surface modi fi cation; excellent cyclability; ENHANCED ELECTROCHEMICAL PERFORMANCE; IN-SITU; STORAGE PERFORMANCE; REDOX ACTIVITY; ANIONIC REDOX; OXIDE; LI1.2MN0.54NI0.13CO0.13O2; NANOTUBES; ORIGIN; RAMAN;
D O I：
10.1021/acsami.2c03073
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
With the increasing demand for high energy density and rapid charging performance, Li-rich materials have been the up and coming cathodes for next-generation lithium-ion batteries. However, because of oxygen evolution and structural instability, the commercialization of Li-rich materials is extremely retarded by their poor electrochemical performances. In this work, Li-deficient materials Li0.3NbO2 and (Nb0.62Li0.15)TiO3 are applied to functionalize the surface of Li1.2Mn0.54Ni0.13Co0.13O2, aiming to suppress oxygen evolution and increase structural stability in LIBs. In addition, a fast Li-ion transport channel is beneficial to enhance Li+ diffusion kinetics. The results demonstrate that the electrodes decorated with Li0.3NbO2 and (Nb0.62Li0.15)TiO3 materials exhibit more stable cycling stability after long-term cycling and outstanding rate capability.
引用
收藏
页码：30133 / 30143
页数：11
相关论文
共 60 条
[1]   Demonstrating oxygen loss and associated structural reorganization in the lithium battery cathode Li[Ni0.2Li0.2Mn0.6]O2 [J].
Armstrong, A. Robert ;
Holzapfel, Michael ;
Novak, Petr ;
Johnson, Christopher S. ;
Kang, Sun-Ho ;
Thackeray, Michael M. ;
Bruce, Peter G. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (26) :8694-8698
[2]   Direct Quantification of Anionic Redox over Long Cycling of Li-Rich NMC via Hard X-ray Photoemission Spectroscopy [J].
Assat, Gaurav ;
Iadecola, Antonella ;
Foix, Dominique ;
Dedryvere, Remi ;
Tarascon, Jean-Marie .
ACS ENERGY LETTERS, 2018, 3 (11) :2721-2728
[3]   Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries [J].
Assat, Gaurav ;
Tarascon, Jean-Marie .
NATURE ENERGY, 2018, 3 (05) :373-386
[4]   Glass-like thermal conductivity of Nd2/3-xLi3xTiO3 bulk ceramics with nanochessboard superlattice structure [J].
Ba, Yaoshuai ;
Wan, Chunlei ;
Wang, Yifeng ;
Norimatsu, Wataru ;
Kusunoki, Michiko ;
Koumoto, Kunihito .
MATERIALS LETTERS, 2013, 97 :191-194
[5]  
BELZONS M, 1976, CR ACAD SCI B PHYS, V283, P241
[6]   AES AND XPS ANALYSIS OF THE INTERACTION OF TI WITH SI AND SIO2 DURING RTA [J].
BENDER, H ;
CHEN, WD ;
PORTILLO, J ;
VANDENHOVE, L ;
VANDERVORST, W .
APPLIED SURFACE SCIENCE, 1989, 38 (1-4) :37-47
[7]   Li/Fe substitution in Li-rich Ni, Co, Mn oxides for enhanced electrochemical performance as cathode materials [J].
Billaud, Juliette ;
Sheptyakov, Denis ;
Sallard, Sebastien ;
Leanza, Daniela ;
Talianker, Michael ;
Grinblat, Judith ;
Sclar, Hadar ;
Aurbach, Doron ;
Novak, Petr ;
Villevieille, Claire .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (25) :15215-15224
[8]   Effect of Li3PO4 coating of layered lithium -rich oxide on electrochemical performance [J].
Chen, Dongrui ;
Zheng, Feng ;
Li, Liu ;
Chen, Min ;
Zhong, Xiaoxin ;
Li, Weishan ;
Lu, Li .
JOURNAL OF POWER SOURCES, 2017, 341 :147-155
[9]   Pseudo-Bonding and Electric-Field Harmony for Li-Rich Mn-Based Oxide Cathode [J].
Chen, Jun ;
Zou, Guoqiang ;
Deng, Wentao ;
Huang, Zhaodong ;
Gao, Xu ;
Liu, Cheng ;
Yin, Shouyi ;
Liu, Huanqing ;
Deng, Xinglan ;
Tian, Ye ;
Li, Jiayang ;
Wang, Chiwei ;
Wang, Di ;
Wu, Hanwen ;
Yang, Li ;
Hou, Hongshuai ;
Ji, Xiaobo .
ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (46)
[10]   Al2O3-coated Li1.2Mn0.54Ni0.13Co0.13O2 nanotubes as cathode materials for high-performance lithium-ion batteries [J].
Chen, Yangwen ;
Wang, Xinchang ;
Zhang, Jiajia ;
Chen, Baiyuan ;
Xu, Junmin ;
Zhang, Sen ;
Zhang, Liwei .
RSC ADVANCES, 2019, 9 (04) :2172-2179
123456