A new electrochemical sensor for extra-virgin olive oils classification

被引:6
作者
Zappi, D. [1 ]
Sadun, C. [1 ]
Gontrani, L. [2 ]
Dini, D. [1 ]
Antonelli, M. L. [1 ]
机构
[1] Univ Roma La Sapienza, Chem Dept, Piazzale Aldo Moro 5, I-00185 Rome, Italy
[2] Univ Bologna, Dept Chem Giacomo Ciamician, V F Selmi 2, I-40126 Bologna, Italy
关键词
Olive oils; Cultivar; Sensor; Bio-based RTIL; Nanomaterials; Screen-printed electrode; TEMPERATURE IONIC LIQUIDS; CHROMATOGRAPHY; NANOMATERIALS; CULTIVAR;
D O I
10.1016/j.foodcont.2019.106903
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
A screen-printed electrode was modified using multi-walled carbon nanotubes (MWCNT) and titanium oxide nanoparticles (TiO2), with a bio-based ionic liquid (RTIL) as a drop-casting medium. The RTILs here used have been proved to be useful for immobilizing nanomaterials on the working electrode surface. The proposed platform has been used to analyze extra-virgin olive oils (EVOOs), produced with olives of known cultivar and geographic origin. The EVOOs were produced with the olives that have been collected in the Italian region of Lazio during 2016, 2017 and 2018 harvesting seasons. The analyses of the oils were done by means of cyclic voltammetry measures. The results here obtained encourage the establishment of criteria for the classification of oils in terms of the corresponding cultivar. Both the electrode modification and the olive oil analysis do not involve any organic solvents. Therefore, the proposed approach represents an environmentally friendly method for field analyses of EVOOs.
引用
收藏
页数:6
相关论文
共 14 条
[1]   Comparison of phenolic compounds profile and antioxidant properties of different sweet cherry (Prunus avium L.) varieties [J].
Acero, Nuria ;
Gradillas, Ana ;
Beltran, Marta ;
Garcia, Antonia ;
Munoz Mingarro, Dolores .
FOOD CHEMISTRY, 2019, 279 :260-271
[2]  
[Anonymous], COMMITTEE COMMON ORG
[3]   Effects of Cultivars and Location on Quality, Phenolic Content and Antioxidant Activity of Extra-Virgin Olive Oils [J].
Baiano, Antonietta ;
Terracone, Carmela ;
Viggiani, Ilaria ;
Del Nobile, Matteo Alessandro .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2013, 90 (01) :103-111
[4]   Combining chromatography and chemometrics for the characterization and authentication of fats and oils from triacylglycerol compositional data-A review [J].
Bosque-Sendra, Juan M. ;
Cuadros-Rodriguez, Luis ;
Ruiz-Samblas, Cristina ;
de la Mata, A. Paulina .
ANALYTICA CHIMICA ACTA, 2012, 724 :1-11
[5]   Mediterranean Diet and Oxidation: Nuts and Olive Oil as Important Sources of Fat and Antioxidants [J].
Bullo, Monica ;
Lamuela-Raventos, Rosa ;
Salas-Salvado, Jordi .
CURRENT TOPICS IN MEDICINAL CHEMISTRY, 2011, 11 (14) :1797-1810
[6]   Cholinium-amino acid based ionic liquids: a new method of synthesis and physico-chemical characterization [J].
De Santis, Serena ;
Masci, Giancarlo ;
Casciotta, Francesco ;
Caminiti, Ruggero ;
Scarpellini, Eleonora ;
Campetella, Marco ;
Gontrani, Lorenzo .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (32) :20687-20698
[7]   Monovarietal extra-virgin olive oil classification: a fusion of human sensory attributes and an electronic tongue [J].
Dias, Luis G. ;
Rodrigues, Nuno ;
Veloso, Ana C. A. ;
Pereira, Jose A. ;
Peres, Antonio M. .
EUROPEAN FOOD RESEARCH AND TECHNOLOGY, 2016, 242 (02) :259-270
[8]   Single-cultivar extra virgin olive oil classification using a potentiometric electronic tongue [J].
Dias, Luis G. ;
Fernandes, Andreia ;
Veloso, Ana C. A. ;
Machado, Adelio A. S. C. ;
Pereira, Jose A. ;
Peres, Antonio M. .
FOOD CHEMISTRY, 2014, 160 :321-329
[9]   Olive oil characterization and classification by 13C NMR with a polarization transfer technique: A comparison with gas chromatography and 1H NMR [J].
Merchak, Noelle ;
Rizk, Toufic ;
Silvestre, Virginie ;
Remaud, Gerald S. ;
Bejjani, Joseph ;
Akoka, Serge .
FOOD CHEMISTRY, 2018, 245 :717-723
[10]   Application of room temperature ionic liquids to the development of electrochemical lipase biosensing systems for water-insoluble analytes [J].
Pauliukaite, Rasa ;
Doherty, Andrew P. ;
Murnaghan, Kevin D. ;
Brett, Christopher M. A. .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2011, 656 (1-2) :96-101