Urease-catalyzed carbonate precipitation inside the restricted volume of polyelectrolyte capsules

被引：84
作者：
Antipov, A
Shchukin, D
Fedutik, Y
Zanaveskina, I
Klechkovskaya, V
Sukhorukov, G [1 ]
Möhwald, H
机构：
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
[2] Phys Chem Res Inst, Minsk 220050, BELARUS
[3] Russian Acad Sci, Inst Crystallog, Moscow, Russia
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2003年 / 24卷 / 03期
关键词：
biomimetic synthesis; biomineralization; CaCO3; microencapsulation; polyelectrolyte capsule; urease;
D O I：
10.1002/marc.200390041
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new biomimetic approach for performing CaCO3 synthesis exclusively inside micron-sized polyelectrolyte capsules, based on the fermentative formation of a precipitative agent (CO32- anion) by urease-catalyzed urea hydrolysis, was developed. Precipitated CaCO3 completely fills the interior capsule volume and has a metastable waterite phase.
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收藏
页码：274 / 277
页数：4
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