Homogeneous catalysis. Mechanisms of the catalysed Mukaiyama cross-aldol reaction

被引：12
|
作者：
Ellis, WW [1 ]
Bosnich, B [1 ]
机构：
[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 02期
关键词：
D O I：
10.1039/a705801b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
It is shown that [2 + 2] addition intermediates can form reversibly in the catalysed Mukaiyama reaction; these serve to prevent formation of the catalyst Me3Si+ and the reactivities of the [2 + 2] intermediates can affect the enantioselectivity of the reaction.
引用
收藏
页码：193 / 194
页数：2
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