Distinction between the weak hydrogen bond and the van der Waals interaction

被引：655

作者：

Steiner, T

Desiraju, GR

机构：

[1] Free Univ Berlin, Inst Kristallog, D-14195 Berlin, Germany

[2] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 08期

关键词：

D O I：

10.1039/a708099i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The angular distributions of C-H ... O interactions for different types of C-H groups show that the directionality decreases with decreasing C-H polarisation, but that it is still clearly recognisable for methyl groups; for C-H ... H-C van der Waals contacts, in contrast, isotropic angular characteristics are observed.

引用

页码：891 / 892

页数：2

共 19 条

[1] ALLEN FH, 1993, CHEM DESIGN AUTOMATI, V8, P1
[2] A SURVEY OF C-H GROUPS AS PROTON DONORS IN HYDROGEN BONDING
ALLERHAND, A
SCHLEYER, PV
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (12) : 1715 - +
[3] VAN DER WAALS VOLUMES + RADII
BONDI, A
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) : 441 - +
[4] Cotton FA, 1997, CHEM COMMUN, P1673
[5] THE C-H...O HYDROGEN-BOND IN CRYSTALS - WHAT IS IT
DESIRAJU, GR
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (10) : 290 - 296
[6] The C-H center dot center dot center dot O hydrogen bond: Structural implications and supramolecular design
Desiraju, GR
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (09) : 441 - 449
[7] Donohue J, 1968, STRUCTURAL CHEM MOL, P443
[8] JEFFREY A, 1991, HYDROGEN BONDING BIO
[9] NONLINEARITY OF HYDROGEN-BONDS IN MOLECULAR-CRYSTALS
KROON, J
KANTERS, JA
[J]. NATURE, 1974, 248 (5450) : 667 - 669
[10] Madhavi NNL, 1997, CHEM COMMUN, P1953

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