Bi- and tri-nuclear ruthenium(II) complexes containing tetrapyridophenazine as a rigid bridging ligand

被引：20

作者：

Bonhôte, P

Lecas, A

Amouyal, E

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

[2] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland

[3] Univ Paris Sud, CNRS, URA 75, Lab Physicochim Rayonnements, F-91405 Orsay, France

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 08期

关键词：

D O I：

10.1039/a709013g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rigid, aromatic bis-tridentate bridging ligand tetrapyrido[2,3-a: 3',2'-c:2 ",3 "-h:3''',2'''-j]phenazine (tpp) allowed the preparation of linear, stable bi-and tri-nuclear complexes of ruthenium(II) exhibiting low energy Ru --> tpp MLCT absorptions and a strong electronic coupling in the mixed-valence state.

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页码：885 / 886

页数：2

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