Diiodido[4′-(4-pyridyl)-2,2′:6′,2"-terpyridine-κ3 N,N′,N"]copper(II)

被引：0
作者：
Chen, Feng-Tao [1 ,2 ]
机构：
[1] Zhejiang Sci Tech Univ, Dept Appl Chem, Hangzhou 310018, Zhejiang, Peoples R China
[2] Zhejiang Sci Tech Univ, Key Lab Adv Text Mat & Mfg Technol, Minist Educ, Hangzhou 310018, Zhejiang, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
COMPLEXES;
D O I：
10.1107/S1600536810020635
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The CuII atom in the title compound, [CuI2(C 20H14N4)], has a distorted square-pyramidal coordination formed by the N atoms of the tridentate 4′-(4-pyridyl)-2, 2′:6′2′′-terpyridine (pyterpy) ligand and two I atoms; one of the I atoms is in the apical position. In contrast to other known square-pyramidal diiodido-and dibromidocopper complexes of the pyterpy ligand in which metal-halogen distances are significantly different, in the title compound the apical and equatorial Cu-I bonds are almost identical [2.6141 (8) and 2.6025 (8) Å, respectively].
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页码：M755 / U419
页数：9
相关论文
共 9 条
[1]  
Bruker, 1998, SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System
[2]   Hydrothermal synthesis of copper complexes of 4′-pyridyl terpyridine:: From discrete monomer to zigzag chain polymer [J].
Feng, Hua ;
Zhou, Xiao-Ping ;
Wu, Tao ;
Li, Dan ;
Yin, Ye-Gao ;
ng, Seik We Ng .
INORGANICA CHIMICA ACTA, 2006, 359 (12) :4027-4035
[3]   Ligand-controlled mixed-valence copper rectangular grid-type coordination polymers based on pyridylterpyridine [J].
Hou, L ;
Li, D ;
Shi, WJ ;
Yin, YG ;
Ng, SW .
INORGANIC CHEMISTRY, 2005, 44 (22) :7825-7832
[4]   Diiodo(4′-phenyl-2,2′:6′,2"-terpyridine-κ3N)-copper(II) [J].
Hou, L ;
Li, D ;
Wu, T ;
Yin, YG ;
Ng, SW .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 :M1181-M1182
[5]   AN UNUSUAL GEOMETRY OF 5-COORDINATE COPPER(II) - THE STRUCTURE OF CU(TERPY)I2 AND SPECTROSCOPIC INVESTIGATIONS OF COMPLEXES CU(TERPY)X2(X-I, NCS) [J].
KUTOGLU, A ;
ALLMANN, R ;
FOLGADO, JV ;
ATANASOV, M ;
REINEN, D .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (09) :1193-1199
[6]  
Sheldrick G.M., 1996, SADABS
[7]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[8]   Supramolecular assembly driven by hydrogen-bonding and π-π stacking interactions based on copper(II)-terpyridyl complexes [J].
Shi, Wen-Juan ;
Hou, Lei ;
Li, Dan ;
Yin, Ye-Gao .
INORGANICA CHIMICA ACTA, 2007, 360 (02) :588-598
[9]   A rare chiral self-catenated network formed by two cationic and one anionic frameworks [J].
Zhang, Shi-Shen ;
Zhan, Shun-Ze ;
Li, Mian ;
Peng, Rong ;
Li, Dan .
INORGANIC CHEMISTRY, 2007, 46 (11) :4365-4367
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