Crystal structure of Tutton's salts K2[MII(H2O)6](SeO4)2, MII = Co, Ni, Zn and refinement of the crystal structure of potassium hexaaquamagnesium(II) selenate, K2[Mg(H2O)6](SeO4)2

被引：14

作者：

Euler, Harald ^{[1
]}

Barbier, Bruno ^{[1
]}

Meents, Alke ^{[2
]}

Kirfel, Armin ^{[2
]}

机构：

[1] Univ Bonn, Steinmann Inst, D-53115 Bonn, Germany

[2] DESPA, HASYLAB, D-22607 Hamburg, Germany

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES | 2009年 / 224卷 / 03期

关键词：

FE;

D O I：

10.1524/ncrs.2009.0156

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

H12K2MgO14Se2, monoclinic, P12(1)/a1 (no. 14), a = 9.264(l) angstrom, b = 12.42 1 (1) angstrom, c = 6.2514(8) angstrom, beta = 104.29(1)degrees, V = 697.1 angstrom(3), Z = 2, R-gt(F) = 0.0 17, wR(ref)(F-2) = 0.035, T = 295 K. H12CoK2O14Se2, monoclinic, P12(1) /a1 (no. 14), a = 9.226(l) angstrom, b = 12.375(l) angstrom, c = 6.2768(7) angstrom, beta = 104.210(9)degrees, V = 694.8 angstrom(3) , Z = 2, R-gt(F) = 0.029, wR(ref)(F-2) = 0.074, T = 295 K. H12K2NiO14Se2, monoclinic, P12(1) /a1 (no. 14), a = 9.179(2) angstrom, b = 12.367(3) angstrom, c = 6.254(2) angstrom, beta = 104.46(2)degrees, V = 687.5 angstrom(3), Z = 2, R-gt(F) = 0.020, WRref (F-2) = 0.052, T = 295 K. H12K2O14Se2Zn, monoclinic, P12(1) /a1 (no. 14), a = 9.212(1) angstrom, b = 12.39 1 (1) angstrom, c = 6.2780(8) angstrom, beta = 104.20(1)degrees, V = 694.7 angstrom(3), Z = 2, R-gt(F) = 0.0 16, wR(ref)(F-2) = 0.034, T= 295 K.

引用

页码：351 / 354

页数：4

共 11 条

[1]

Brandenburg K., 2012, DIAMOND VISUAL CRYST

[2] Utility and synthetic uses of Mannich reaction: An efficient route for synthesis of thiadiazino-[1,3,5][3,2-a]benzimidazoles [J].