Influence of oxygen on band alignment at the organic/aluminum interface

被引:24
作者
Blyth, RIR [1 ]
Sardar, SA [1 ]
Netzer, FP [1 ]
Ramsey, MG [1 ]
机构
[1] Karl Franzens Univ Graz, Inst Expt Phys, A-8010 Graz, Austria
关键词
D O I
10.1063/1.1289497
中图分类号
O59 [应用物理学];
学科分类号
摘要
The presence of adventitious oxygen is inevitable when organic/metal interfaces are formed by evaporation in high vacuum (10(-6) mbar.). In this letter, we highlight the importance of this oxygen for band alignment, and hence, performance, in organic-based devices. The influence of controlled amounts of oxygen on band alignment in benzene/aluminum model cathode interfaces has been studied using ultraviolet photoemission in ultrahigh vacuum. We show that even small amounts of oxygen significantly lower the aluminum work function with concomitant improvement in band alignment. (C) 2000 American Institute of Physics. [S0003-6951(00)02534-1].
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收藏
页码:1212 / 1214
页数:3
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