Long range nonadiabatic couplings and the cluster-size dependence of the lifetime of excited hydrated electrons

被引：10
作者：
Fischer, Sighart F. [1 ]
Dietz, W. [1 ]
机构：
[1] Tech Univ Munich, Phys Dept T38, D-85748 Garching, Germany
来源：
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2007年 / 221卷 / 05期
关键词：
excited hydrated electrons; anion water clusters; internal conversion; nonadiabatic coupling; solvation dynamics;
D O I：
10.1524/zpch.2007.221.5.585
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The recently observed linear dependence of the lifetime of excited hydrated electrons upon the inverse of the cluster size is explained in terms of a nonadiabatic long range coupling mechanism. It is due to dipolar interactions between the p -> s transition and the excitation of the infrared active modes of the solvent water molecules.
引用
收藏
页码：585 / 595
页数：11
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