Palladium-catalyzed cross-coupling reactions of allylic halides and acetates with indium organometallics

被引：45

作者：

Rodríguez, D ^{[1
]}

Sestelo, JP ^{[1
]}

Sarandeses, LA ^{[1
]}

机构：

[1] Univ A Coruna, Dept Quim Fundamental, E-15071 La Coruna, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 23期

关键词：

D O I：

10.1021/jo0491511

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium(0)-catalyzed cross-coupling reaction of allylic halides and acetates with indium organometallics is reported. In this synthetic transformation, triorganoindium compounds and tetraorganoindates (aryl, alkenyl, and methyl) react with cinnamyl and geranyl halides and acetates to afford the S(N)2 product regioselectively and in good yield. The reaction proceeds with net inversion of the stereochemical configuration.

引用

页码：8136 / 8139

页数：4

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