Growing Atmospheric Emissions of Sulfuryl Fluoride

被引：16

作者：

Gressent, A. ^{[1
]}

Rigby, M. ^{[2
]}

Ganesan, A. L. ^{[3
]}

Prinn, R. G. ^{[1
]}

Manning, A. J. ^{[4
]}

Muehle, J. ^{[5
]}

Salameh, P. K. ^{[5
]}

Krummel, P. B. ^{[6
]}

Fraser, P. J. ^{[6
]}

Steele, L. P. ^{[6
]}

Mitrevski, B. ^{[6
]}

Weiss, R. F. ^{[5
]}

Harth, C. M. ^{[5
]}

Wang, R. H. ^{[5
]}

O'Doherty, S. ^{[2
]}

Young, D. ^{[3
]}

Park, S. ^{[7
]}

Li, S. ^{[8
]}

Yao, B. ^{[9
]}

Reimann, S. ^{[10
]}

Vollmer, M. K. ^{[10
]}

Maione, M. ^{[11
,12
]}

Arduini, J. ^{[11
,12
]}

Lunder, C. R. ^{[13
]}

机构：

[1] MIT, Ctr Global Change Sci, 77 Massachusetts Ave, Cambridge, MA 02139 USA

[2] Univ Bristol, Sch Chem, Bristol, Avon, England

[3] Univ Bristol, Sch Geog Sci, Bristol, Avon, England

[4] Met Off, London, England

[5] Univ Calif San Diego, Scripps Inst Oceanog, San Diego, CA 92103 USA

[6] CSIRO Oceans & Atmosphere, Climate Sci Ctr, Aspendale, Vic, Australia

[7] Kyungpook Natl Univ, Coll Nat Sci, Dept Oceanog, Daegu, South Korea

[8] Natl Inst Meteorol Sci, Climate Res Div, Seogwipo, South Korea

[9] China Meteorol Adm, Meteorol Observat Ctr, Beijing, Peoples R China

[10] Empa, Swiss Fed Labs Mat Sci & Technol, Lab Air Pollut & Environm Technol, Dubendorf, Switzerland

[11] Univ Urbino, Dept Pure & Appl Sci, Urbino, Italy

[12] CNR, Inst Atmospher Sci & Climat, Bologna, Italy

[13] Norwegian Inst Air Res, Kjeller, Norway

来源：

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES | 2021年 / 126卷 / 09期

基金：

美国国家航空航天局; 新加坡国家研究基金会; 英国自然环境研究理事会; 美国海洋和大气管理局;

关键词：

AGAGE; emissions; global atmosphere; SO2F2; GASES; HALOCARBONS; LIFETIMES; CHEMISTRY; HISTORY; CHINA;

D O I：

10.1029/2020JD034327

中图分类号：

P4 [大气科学（气象学）];

学科分类号：

0706 ; 070601 ;

摘要：

The potent greenhouse gas sulfuryl fluoride (SO2F2) is increasingly used as a fumigant, replacing methyl bromide, whose structural and soil fumigation uses have been phased out under the Montreal Protocol. We use measurements on archived air samples and in situ observations from the Advanced Global Atmospheric Gases Experiment (AGAGE) and a box model of the global atmosphere to show a global increase of SO2F2 mole fraction from 0.3 +/- 0.02 to 2.5 +/- 0.08 ppt along with a global increase in emissions from 0.5 +/- 0.4 Gg yr(-1) to 2.9 +/- 0.4 Gg yr(-1) from 1978 to 2019. Based on a hybrid model incorporating bottom-up industry data and a top-down downscaling approach, we estimate the spatial distribution and trend in SO2F2 regional emissions between 2000 and 2019 and propose that the global emissions increase is driven by the growing use of SO2F2 in structural fumigation in North America and in postharvest treatment of grains and other agricultural products worldwide.

引用

页数：11

共 46 条

[1]

[Anonymous], 2006, SUMM PEST US REP DAT

[2] Automated Measurement of Nitrogen Trifluoride in Ambient Air [J].

Arnold, Tim ;

Muehle, Jens ;

Salameh, Peter K. ;

Harth, Christina M. ;

Ivy, Diane J. ;

Weiss, Ray F. .

ANALYTICAL CHEMISTRY, 2012, 84 (11) :4798-4804

[3]

Buckley S., 2012, P 6 INT C CONTROLLED, P241

[4]

Burkholder J., 2015, CHEM KINETICS PHOTOC

[5] Evaluation of sulfuryl fluoride as a soil fumigant in China [J].

Cao, Aocheng ;

Guo, Meixia ;

Yan, Dongdong ;

Mao, Liangang ;

Wang, Qiuxia ;

Li, Yuan ;

Duan, Xiayu ;

Wang, Peisheng .

PEST MANAGEMENT SCIENCE, 2014, 70 (02) :219-227

[6]

Carpenter L.J., 2014, SCI ASSESSMENT OZONE, P88

[7]

CIESIN, 2018, **DATA OBJECT**, DOI [10.7927/H49C6VHW, DOI 10.7927/H49C6VHW]

[8] Reducing Energy Demand: What Are the Practical Limits? [J].

Cullen, Jonathan M. ;

Allwood, Julian M. ;

Borgstein, Edward H. .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2011, 45 (04) :1711-1718

[9] THE ATMOSPHERIC LIFETIME EXPERIMENT .3. LIFETIME METHODOLOGY AND APPLICATION TO 3 YEARS OF CFCL3 DATA [J].

CUNNOLD, DM ;

PRINN, RG ;

RASMUSSEN, RA ;

SIMMONDS, PG ;

ALYEA, FN ;

CARDELINO, CA ;

CRAWFORD, AJ ;

FRASER, PJ ;

ROSEN, RD .

JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS, 1983, 88 (NC13) :8379-8400

[10] The atmospheric chemistry of sulphuryl fluoride, SO2F2 [J].

Dillon, T. J. ;

Horowitz, A. ;

Crowley, J. N. .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2008, 8 (06) :1547-1557

← 1 2 3 4 5 →