共 23 条
Aggregation behavior of tetraenoic fatty acids in aqueous solution
被引:9
作者:
Wang, Yonghui
[1
]
Ma, Jianguo
[1
]
Cheon, Hwan-Sung
[1
]
Kishi, Yoshito
[1
]
机构:
[1] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA
关键词:
aggregation;
chromophores;
doping;
fatty acids;
micelles;
D O I:
10.1002/anie.200603979
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
(Chemical Equation Presented) Why so blue? Unique blue-shifted UV absorptions were used to follow the aggregation of C24 tetraene fatty acids in aqueous solution. Aggregation takes place through three distinct states (i.e. K→T1→T2; see picture). It is suggested that all of these aggregates are lamellar-type in a local sense but differ in the packing mode of the fatty acid backbone. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码:1333 / 1336
页数:4
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