Aggregation behavior of tetraenoic fatty acids in aqueous solution

被引:9
作者
Wang, Yonghui [1 ]
Ma, Jianguo [1 ]
Cheon, Hwan-Sung [1 ]
Kishi, Yoshito [1 ]
机构
[1] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA
关键词
aggregation; chromophores; doping; fatty acids; micelles;
D O I
10.1002/anie.200603979
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Why so blue? Unique blue-shifted UV absorptions were used to follow the aggregation of C24 tetraene fatty acids in aqueous solution. Aggregation takes place through three distinct states (i.e. K→T1→T2; see picture). It is suggested that all of these aggregates are lamellar-type in a local sense but differ in the packing mode of the fatty acid backbone. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1333 / 1336
页数:4
相关论文
共 23 条
[21]   Newly found 2-N-acetyl-2,6-dideoxy-β-glucopyranose containing methyl glucose polysaccharides in M-bovis BCG:: revised structure of the mycobacterial methyl glucose lipopolysaccharides [J].
Tuffal, G ;
Albigot, R ;
Rivière, M ;
Puzo, G .
GLYCOBIOLOGY, 1998, 8 (07) :675-684
[22]   PHOTOCHEMISTRY AND PHOTOPHYSICS OF TRANS-STILBENE AND RELATED ALKENES IN SURFACTANT ASSEMBLIES [J].
WHITTEN, DG .
ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (09) :502-509
[23]   INTERACTION OF MYCOBACTERIAL POLYMETHYLPOLYSACCHARIDES WITH PARANARIC ACID AND PALMITOYL-COENZYME-A - STRUCTURAL SPECIFICITY AND MONOMERIC DISSOCIATION-CONSTANTS [J].
YABUSAKI, KK ;
BALLOU, CE .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1978, 75 (02) :691-695