Aggregation behavior of tetraenoic fatty acids in aqueous solution

被引:9
作者
Wang, Yonghui [1 ]
Ma, Jianguo [1 ]
Cheon, Hwan-Sung [1 ]
Kishi, Yoshito [1 ]
机构
[1] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA
关键词
aggregation; chromophores; doping; fatty acids; micelles;
D O I
10.1002/anie.200603979
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Why so blue? Unique blue-shifted UV absorptions were used to follow the aggregation of C24 tetraene fatty acids in aqueous solution. Aggregation takes place through three distinct states (i.e. K→T1→T2; see picture). It is suggested that all of these aggregates are lamellar-type in a local sense but differ in the packing mode of the fatty acid backbone. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1333 / 1336
页数:4
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